Institut für Anorganische Chemie | Universität Würzburg | D-97074 Würzburg

The Braunschweig Group


Research in the Braunschweig group covers a wide range of organometallic and main group element chemistry. Motivation for our work arises from the fundamental interest in novel molecular species, and much emphasis lies with the elucidation of their detailed electronic structure and reactivity patterns, thus disclosing potential applications in organic synthesis, catalysis, or materials science. Commonly, sophisticated synthetic protocols, as well as state-of-the-art analytical and computational methods are applied to meet these goals. Significant achievements over the past decades were made in various independent, highly topical and competitive sub-areas of (i) organometallic chemistry such as metal boron complexes (borane, boryl, borylene, boride, oxoboryl), metallo-arenophanes, or metal-only Lewis pairs, and (ii) main group element chemistry such as novel boron heterocycles (boroles, azaborinines, etc.) and boron boron multiple bonded species (diborenes, diborynes).

Selected Recent Publications



Z. Huang, S. Wang, R. D. Dewhurst, N. V. Ignat'ev, M. Finze, H. Braunschweig 

Boron: Its Role in Energy-Related Processes and Applications

Angew. Chem. Int. Ed. 202059, 8800–8816[pdf]




J. H. Müssig, P. Lisinetskaya, R. D. Dewhurst, R. Bertermann, M. Thaler, R. Mitrić, H. Braunschweig

Tetraiododiborane(4) (B2I4) is an Polymer based on sp3 Boron in the Solid State

Angew. Chem. Int. Ed. 202059, 5531–5535[pdf]




C. Brunecker, J. H. Müssig, M. Arrowsmith, F. Fantuzzi, A. Stoy, J. Böhnke, A. Hofmann, R. Bertermann, B. Engels, H. Braunschweig 

Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes

Chem. Eur. J. 202026, 8518–8523[pdf]




J. Merz, M. Dietz, Y. Vonhausen, F. Wöber, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Moos, M. Holzapfel, C. Lambert, T. B. Marder 

Synthesis, Photophysical and Electronic Properties of New Red-to-NIR Emitting Donor-Acceptor Pyrene Derivatives
Chem. Eur. J. 202026, 438–453[pdf]



G. Bélanger-Chabot, H. Braunschweig 

Hexahalodiborate Dianions: A New Family of Binary Boron Halides

Angew. Chem. Int. Ed. 201958, 14270–14274[pdf]

The homepage for our newly-established research institute - the Institute for Sustainable Chemistry & Catalysis with Boron (ICB) is now online. 

Visit the ICB homepage.