The Braunschweig Group
Research in the Braunschweig group covers a wide range of organometallic and main-group element chemistry. Motivation for our work arises from a fundamental interest in novel molecular species, and much emphasis lies with the elucidation of their detailed electronic structure and reactivity patterns, thereby disclosing potential applications in organic synthesis, catalysis, and materials science. Sophisticated synthetic protocols as well as state-of-the-art analytical and computational methods are applied to meet these goals. Significant achievements over the past decades have been made in independent, highly topical and competitive areas of research, such as: (i) the synthesis and reactivity of reactive low-valent main-group compounds (e.g. transition metal borylene complexes and metal-free borylenes, diborenes, diborynes, beryllium(0) and beryllium(I) compounds, alumenes and dialumenes), (ii) small-molecule activation (e.g. N2, CO2, CO) by low-valent boron species, (iii) the synthesis of novel and photophysically-active boron, beryllium and aluminum heterocycles (e.g. boroles, alumoles, berylloles, azaborinines, diborabenzenes), (iv) the study of highly reactive small boron-containing molecules (e.g. tetrahalodiboranes, hexahalodiborates), and (v) the synthesis of boron-chain compounds and boron-containing polymers.
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Holger Braunschweig has recently been awarded the prestigious ENI award.
Watch the ENI prize ceremony with Sergio Mattarella, the current president of Italy.
Selected recent publications
M. Weber, T. Kupfer, M. Arrowsmith, R. D. Dewhurst, M. Rang, B. Ritschel, S. Titlbach, M. Ernst, M. Oliveira Rodrigues, E. N. da Silva Júnior, H. Braunschweig
Bypassing Ammonia: From N2 to Nitrogen Heterocycles without
N1 Intermediates or
Transition Metals
Angew. Chem. 2024, 136, e202402777; [pdf] Angew. Chem. Int.
Ed. 2024, 63, e202402777. [pdf]
L. Euringer, M. Holzapfel, I. Krummenacher, M. Franz, S. Richert, H. Braunschweig, C. Lambert
Tuning Electron Transfer Coupling and Exchange Interaction in Bis-triarylamine Radical Cations and Dications by Bridge Electron Density
J. Am. Chem. Soc. 2024, 146, 27679–27689. [pdf]
C. Czernetzki, T. Kunz, S. Huynh, A. Lamprecht, J. Sprenger, M. Finze, M. Arrowsmith, H. Braunschweig
Synthesis and Reactivity of Tricoordinate Organoberyllium Azides
Angew. Chem. 2024, 136, e202401279; Angew. Chem. Int. Ed. 2024, 63, e202401279. [pdf]
D. Dhara, L. Endres, I. Krummenacher, M. Arrowsmith, R. D. Dewhurst, B. Engels, R. Bertermann, M. Finze, S. Demeshko, F. Meyer, F. Fantuzzi, H. Braunschweig
Synthesis and Reactivity of a Dialane-Bridged Diradical
Angew. Chem. 2024, 136, e202401052; Angew. Chem. Int. Ed. 2024, 63, e202401052. [pdf]
C. Czernetzki, M. Arrowsmith, L. Endres, I. Krummenacher, H. Braunschweig
Tricoordinate Beryllium Radicals and Their Reactivity
Inorg. Chem. 2024, 63, 2670–2678. [pdf]