Publications 2010



H. Braunschweig, K. Radacki, A. Schneider
Oxoboryl Complexes: Boron–Oxygen Triple Bonds stabilized in the Coordination Sphere of Platinum
Science 2010, 328, 345–347. [pdf]


Highlighted in:

"Boron-Oxygen Triple Play", S. K. Ritter, C&EN 2010, 88, 8. [link]


"BO Chemistry Comes Full Circle", S. A. Westcott, Angew. Chem. 2010, 122, 9229–9230; [pdf] Angew. Chem. Int. Ed. 2010, 49, 9045–9046. [pdf]


"Entry of boron-oxygen triple bond ligand", H. Maeda, Organomet. News. 2010, 88, 1–3.

Angew. Chem.


S. Bertsch, H. Braunschweig, B. Christ, M. Forster, K. Schwab, K. Radacki
Towards Homoleptic Borylene Complexes: Incorporation of Two Borylene Ligands into a Mononuclear Iridium Species
Angew. Chem. 2010, 122, 9707–9710; [pdf] Angew. Chem. Int. Ed. 2010, 49, 9517–9520. [pdf]



H. Braunschweig, F. Breher, C.-W. Chiu, D. Gamon, D. Nied, K. Radacki
Reduction Chemistry of Ferrocenylborole
Angew. Chem. 2010, 122, 9159–9162; [pdf] Angew. Chem. Int. Ed. 2010, 49, 8975–8978. [pdf]



H. Braunschweig, K. Radacki, A. Schneider
Cyclodimerization of an Oxoboryl Complex Induced by trans Ligand Abstraction (VIP)
Angew. Chem. 2010, 122, 6130–6133; [pdf] Angew. Chem. Int. Ed. 2010, 49, 5993–5996. [pdf]



H. Braunschweig, R. Dewhurst
Fashionably Late: Synthesis and Characterization of Transition-Metal–Fluoroborylene Complexes
Angew. Chem. 2010, 122, 3486–3488; [pdf] Angew. Chem. Int. Ed. 2010, 49, 3412–3414. [pdf]



H. Braunschweig, C.-W. Chiu, K. Radacki, T. Kupfer
Synthesis and Structure of a Carbene-Stabilized π-Boryl Anion (VIP)
Angew. Chem. 2010, 122, 2085–2088; [pdf] Angew. Chem. Int. Ed. 2010, 49, 2041–2044. [pdf]


Highlighted in:

"Cyclopentadienyl-Analoga mit Bor und Blei", L. Jaenicke, Chem. Unserer Zeit 2011, 45, 6–12. [pdf]


"Not just any old anion", K. Nozaki, Nature 2010, 464, 1136–1137. [pdf]


"Nucleophilicity of a Base-Stabilized Borole Anion at the Boron Center", M. Yamashita, Angew. Chem. Int. Ed. 2010, 49, 2474–2475. [pdf]

J. Am. Chem. Soc.


H. Braunschweig, P. Brenner, M. Groß, K. Radacki
Reactivity of [1],[1]Disilamolybdenocenophane towards zerovalent Platinum Complexes
J. Am. Chem. Soc. 2010, 132, 11343–11349. [pdf]

Chem. Commun.


H. Braunschweig, P. Brenner, P. Cogswell, K. Kraft, K. Schwab
Oxidative Addition of the Bismuth-chloride Bond: Synthesis and Structure of trans-[PtCl(PCy3)2{BiCl2}]
Chem. Commun. 2010, 46, 7894–7896. [pdf]



H. Braunschweig, K. Radacki, A. Schneider
Reactivity of an Oxoboryl Complex toward Fluorinated Aryl Boron Reagents
Chem. Commun. 2010, 46, 6473–6475. [pdf]



H. Braunschweig, C.-W. Chiu, K. Radacki, P. Brenner
Platinum substituted boroles
Chem. Commun. 2010, 46, 916–918. [pdf]



H. Braunschweig, K. Radacki, K. Schwab
An early-late heterobimetallic complex with an unsupported dative bond: synthesis and structure of [(Cy3P)2Pt–ZrCl4]
Chem. Commun. 2010, 46, 913–915. [pdf]

Chem. Eur. J.


H. Braunschweig, C.-W. Chiu, J. Wahler, K. Radacki, T. Kupfer
Chemical Reduction and Dimerization of 1-Chloro-2,3,4,5-tetraphenylborole
Chem. Eur. J. 2010, 16, 12229–12233. [pdf]



J. Bauer, H. Braunschweig, P. Brenner, K. Kraft, K. Radacki, K. Schwab
Late transition metal complexes as tunable Lewis-bases
Chem. Eur. J. 2010, 16, 11985–11992. [pdf]



H. Braunschweig, M. Fuß, S. K. Mohapatra, K. Kraft, T. Kupfer, M. Lang, K. Radacki, C. G. Daniliuc, P. G. Jones, M. Tamm
Synthesis and Reactivity of Boron-, Silicon- and Tin-Bridged ansa-Cyclopentadienyl-Cycloheptatrienyl Titanium Complexes (Troticenophanes)
Chem. Eur. J. 2010, 16, 11732–11743. [pdf]



H. Braunschweig, K. Kraft, S. Östreicher, K. Radacki, F. Seeler
Neutral and Anionic Transition-Metal-Base-Stabilized Metalloborylene Complexes
Chem. Eur. J. 2010, 16, 10635–10637 (VIP). [pdf]



T. Arnold, H. Braunschweig, M. Groß, M. Kaupp, R. Müller, K. Radacki
Electronic Structure and Reactivity of a [1],[1]Disilamolybdenocenophane
Chem. Eur. J. 2010, 16, 3014–3020. [pdf]

Chem. Rev.


H. Braunschweig, R. D. Dewhurst, A. Schneider
Electron-Precise Coordination Modes of Boron-Centered Ligands
Chem. Rev. 2010, 110, 3924–3957. [pdf]

Acc. Chem. Res.


H. Braunschweig, T. Kupfer
Non-Iron [n]Metalloarenophanes
Acc. Chem. Res. 2010, 43, 455–465. [pdf]

Inorg. Chem.


K. K. Pandey, P. Patidar, H. Braunschweig
Structure and Bonding Energy Analysis of M-Ga Bonds in Dihalogallyl Complexes [X(PMe3)2M(GaX2)] (M = Ni, Pd, Pt; X = Cl, Br, I)
Inorg. Chem. 2010, 49, 6994–7000. [pdf]



H. Bera, H. Braunschweig, R. Dörfler, T. Kupfer, K. Radacki, F. Seeler
Half-sandwich Tungsten Complexes with Metal- and η5-Cyclopentadienyl-bound Functional Stannyl Groups and their Transformation into Ansa Complexes
Organometallics 2010, 29, 5111–5120. [pdf]



P. Bissinger, H. Braunschweig, T. Kupfer, K. Radacki
Monoborane NHC Adducts in the Coordination Sphere of Transition Metals
Organometallics 2010, 29, 3987–3990. [pdf]



H. Braunschweig, F. Matz, K. Radacki, A. Schneider
Reactivity of Platinum Iminoboryl Complexes toward Covalent Element-Hydrogen Bonds of Opposing Polarity
Organometallics 2010, 29, 3457–3462. [pdf]



F. Bauer, H. Braunschweig, K. Schwab
1,1-Diboration of Isocyanides with [2]Borametalloarenophanes
Organometallics 2010, 29, 934–938. [pdf]

Eur. J. Inorg. Chem.


H. Braunschweig, J. Mies, R. Dörfler, K. Hammond, K. Radacki
Synthesis and Structure of Trisila-bridged ansa Half-sandwich Complexes of Group 6 Metals
Eur. J. Inorg. Chem. 2010, 5383–5385. [pdf]



H. Braunschweig, A. Damme, T. Kupfer
Novel [2]Boraferrocenophane and Diferrocenyldiborane(4) Derivatives
Eur. J. Inorg. Chem. 2010, 4423–4426. [pdf]

J. Organomet. Chem.


H. Bera, H. Braunschweig, A. Oechsner, R. Sigritz, F. Seeler
Synthesis of a Distanna-[2]ferrocenophane and Reactivity of [2]Ferrocenophanes towards elemental Sulfur and Selenium
J. Organomet. Chem. 2010, 695, 2609–2613. [pdf]

Z. anorg. allg. Chem.


H. Braunschweig, K. Kraft, T. Kupfer, E. Siedler
Manganese-σ-Borane Complexes of Dihaloboranes
Z. anorg. allg. Chem. 2010, 636, 2565–2567. [pdf]

Z. Naturforsch.


H. Braunschweig, K. Kraft, K. Radacki, S. Stellwag
Molybdenum-Boron Bonds in the Crystal – Structural Characterization of K[(η5-C5H5)Mo(CO)3] and [(η5-C5H5)(OC)3Mo-B(NMe2)-B(NMe2)Br]
Z. Naturforsch. 2010, 65b, 1073–1076. [pdf]

Acta Cryst.


H. Braunschweig, A. Damme
Acta Cryst. 2010, E66, o3367. [pdf]



H. Braunschweig, R. D. Dewhurst, K. Wagner, K. Schwab
Acta Cryst. 2010, E66, o610. [pdf]

J. Raman Spectrosc.


J. Köhler, S. Lindenmaier, I. Fischer, H. Braunschweig, T. Kupfer, D. Gamon, C.-W. Chiu
Probing Antiaromaticity: Resonance Raman Investigation of a series of differently substituted boroles
J. Raman Spectrosc. 2010, 41, 636–641. [pdf]

Bioorg. Med. Chem.


V. Alptüzün, M. Prinz, V. Hörr, J. Scheiber, K. Radacki, A. Fallarero, P. Vuorela, B. Engels, H. Braunschweig, E. Erciyas, U. Holzgrabe
Interaction of (benzylidene-hydrazono)-1,4-dihydropyridines with beta-amyloid, acetylcholine and butyrylcholine esterases
Bioorg. Med. Chem. 2010, 18, 2049–2059. [pdf]