Publications 2017



[453]

Z. Wang, Y. Zhou, K.-H. Lee, W. H. Lam, R. D. Dewhurst, H. Braunschweig, T. B. Marder, Z. Lin 

DFT studies of dimerization reactions of boroles
2017, submitted.

 

[452]

S. R. Wang, M. Arrowsmith, J. Böhnke, H. Braunschweig, T. Dellermann, R. D. Dewhurst, H. Kelch, I. Krummenacher, J. D. Mattock, J. H. Müssig, T. Thiess, A. Vargas, J. Zhang 

Engineering a Small HOMO-LUMO Gap and Intramolecular B—B Hydroarylation by Diborene/Anthracene Orbital Intercalation
2017, submitted.

 

[451]

B. Borthakur, H. Braunschweig, A. Deißenberger, T. Dellermann, R. D. Dewhurst, I. Krummenacher, M. Nutz, A. K. Phukan, M. Schäfer 

Synthesis and Trapping of Iminoboranes via M=B/C=N Bond Metathesis
2017, submitted.

 

[450]

H. Braunschweig, M. A. Celik, T. Dellermann, G. Frenking, K. Hammond, F. Hupp, H. Kelch, I. Krummenacher, F. Lindl, L. Mailänder, J. H. Müssig, A. Ruppert 

Scope of the Thermal Ring Expansion Reactions of Boroles with Organoazides
2017, submitted.

 

[449]

J. Schäfer, M. Holzapfel, B. Mladenova, D. Kattnig, I. Krummenacher, H. Braunschweig, G. Grampp, C. Lambert 

Tuning Hole Transfer in meta- and para-Conjugated Mixed Valence Compounds by Bridge Substituents 
J. Am. Chem. Soc. 2017, 139accepted.

 

[448]

M. Arrowsmith, J. Böhnke, H. Braunschweig, H. Gao, M.-A. Légaré, V. Paprocki, J. Seufert 

Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes
Chem. Eur. J. 2017, 23accepted.

 

[447]

H. Braunschweig, R. D. Dewhurst, W. E. Ewing, M. Schäfer 

Isolation of a reactive cyclopropane intermediate via a unique catalyst-free spontaneous cyclopropanation step at 0 °C
Chem. Eur. J. 2017, 23accepted.

 

[446]

N. Arnold, R. Bertermann, F. M. Bickelhaupt, H. Braunschweig, M. Drisch, M. Finze, F. Hupp, J. Poater, J. A. P. Sprenger
Formation of a Trifluorophosphane Platinum(II) Complex via P—F Bond Activation of Phosphorus Pentafluoride with a Pt(0) Complex
Chem. Eur. J. 2017, 23accepted.



Angew. Chem.

[445]

H. Braunschweig, I. Krummenacher, C. Lichtenberg, J. D. Mattock, M. Schäfer, U. Schmidt, C. Schneider, T. Steffenhagen, S. Ullrich, A. Vargas 

Dibora[2]ferrocenophane: A Carbene-Stabilized Diborene in a Strained cis-Configuration 
Angew. Chem. 2017, 129, 907–911; [pdf] Angew. Chem. Int. Ed. 2017, 56, 889–892. [pdf]

 

[444]

M. Arrowsmith, H. Braunschweig, T. E. Stennett

Formation and Reactivity of Electron-Precise B—B Single and Multiple Bonds 
Angew. Chem. 2017, 129, 100–120; [pdf] Angew. Chem. Int. Ed. 2017, 56, 96–115. [pdf]



J. Am. Chem. Soc.

[443]

H. Braunschweig, T. Dellermann, R. D. Dewhurst, B. Hupp, T. Kramer, J. Mattock, J. Mies, A. K. Phukan, A. Steffen, A. Vargas 

Strongly Phosphorescent Transition Metal π Complexes of Boron-Boron Triple Bonds

J. Am. Chem. Soc. 2017139, 4887–4893. [pdf]

 

Highlighted in:

"Copper brings glow to triple-bonded boron", D. Bradley, Chemistry World 2017. [link]

 

[442]

H. Braunschweig, I. Krummenacher, M.-A. Légaré, A. Matler, K. Radacki, Q. Ye 

Main-Group Metallomimetics — Unprecedented Transition Metal-like Photolytic CO Substitution at Boron
J. Am. Chem. Soc. 2017139, 1802–1805. [pdf]



Chem. Eur. J.

[441]

M. Arrowsmith, H. Braunschweig, K. Radacki, T. Thiess, A. Turkina 

Facile Access to Electron-Precise Monohydrodiboranes(4), (cis-)1,2-Dihydrodiboranes(4) and a 1,1-Dihydrodiborane(5)
Chem. Eur. J. 201723, 2179–2183. [pdf]