Publications 2008



Angew. Chem.

[154]

H. Braunschweig, M. Groß, K. Radacki, C. Rothgaengel
Intramolecular Activation of a Disila[2]molybdenocenophanedihydride: Synthesis and Structure of a [1],[1]Metalloarenophane
Angew. Chem. 2008, 120, 10127–10129; [pdf] Angew. Chem Int. Ed. 2008, 47, 9979–9981. [pdf]

 

[153]

H. Braunschweig, M. Forster, T. Kupfer, F. Seeler
Borylene Transfer under Thermal Conditions for the Synthesis of Rhodium and Iridium Borylene Complexes
Angew. Chem. 2008, 120, 6070–6072; [pdf] Angew. Chem. Int. Ed. 2008, 47, 5981–5983. [pdf]

 

[152]

H. Braunschweig, R. D. Dewhurst, T. Herbst, K. Radacki
Reactivity of a Terminal Chromium Borylene Complex towards Olefin: Insertion of a Borylene into a C–H Bond
Angew. Chem. 2008, 120, 6067–6069; [pdf] Angew. Chem. Int. Ed. 2008, 47, 5978–5980. [pdf]

 

[151]

H. Braunschweig, M. Burzler, R. D. Dewhurst, K. Radacki
A Linear, Anionic Dimetalloborylene Complex
Angew. Chem. 2008, 120, 5732–5735; [pdf] Angew. Chem. Int. Ed. 2008, 47, 5650–5653. [pdf]

 

[150]

H. Braunschweig, K. Kraft, T. Kupfer, K. Radacki, F. Seeler
B+ in theCoordination Sphere of Two Transition Metals
Angew. Chem. 2008, 120, 5009–5011; [pdf] Angew. Chem. Int. Ed. 2008, 47, 4931–4933. [pdf]

 

[149]

H. Braunschweig, M. Burzler, U. Flierler, J. Henn, D. Leusser, H. Ott, D. Stalke
Electron-Density Investigation of Metal-Metal Bonding in the Dinuclear "Borylene" Complex [{Cp(CO)2Mn}2(μ-BtBu)]
Angew. Chem. 2008, 120, 4393–4397; [pdf] Angew. Chem. Int. Ed. 2008, 47, 4321–4325. [pdf]

 

[148]

C. J. Adams, H. Braunschweig, T. Kupfer, I. Manners, R. Richardson, G. Whittell
Synthesis of a Paramagnetic Polymer by Ring-Opening Polymerization of a Strained [1]Vanadoarenophane (VIP)
Angew. Chem. 2008, 120, 3886–3889; [pdf] Angew. Chem. Int. Ed. 2008, 47, 3826–3829. [pdf]

 

[147]

H. Braunschweig, I. Fernández, G. Frenking, T. Kupfer
Structural Evidence for Antiaromaticity in Free Boroles
Angew. Chem. 2008, 120, 1977–1980; [pdf] Angew. Chem. Int. Ed. 2008, 47, 1951–1954. [pdf]



J. Am. Chem. Soc.

[146]

G. Bringmann, D. Götz, T. Gulder, T. Gehrke, T. Bruhn, T. Kupfer, K. Radacki, H. Braunschweig, A. Heckmann, C. Lambert
Axially Chiral β,β’-Bisporphyrins: Synthesis and Configurational Stability Tuned by the Central Metals
J. Am. Chem. Soc. 2008, 130, 17812–17825. [pdf]

 

[145]

H. Braunschweig, M. Kaupp, C. J. Adams, T. Kupfer, K. Radacki, S. Schinzel
Synthesis, Reactivity and Electronic Structure of [n]Vanadoarenophanes: An Experimental and Theoretical Study
J. Am. Chem. Soc. 2008, 130, 11376–11393. [pdf]

 

[144]

H. Braunschweig, T. Kupfer, K. Radacki, A. Schneider, F. Seeler, K. Uttinger, H. Wu
Synthesis and Reactivity Studies of Iminoboryl Complexes
J. Am. Chem. Soc. 2008, 130, 7974–7983. [pdf]

 

[143]

H. Braunschweig, T. Kupfer
Stoichiometric and Homogeneous-Catalytic Diboration of the N=N Double Bond of Azobenzene
J. Am. Chem. Soc. 2008, 130, 4242–4243. [pdf]



Chem. Commun.

[142]

H. Braunschweig, T. Kupfer
Direct Functionalization at the Boron Centre of Antiaromatic Chloroborole
Chem. Commun. 2008, 4487–4489. [pdf]

 

[141]

L. Apostolico, H. Braunschweig, A. G. Crawford, T. Herbst, D. Rais
Group VI Metal Aminoborylene Complex-Catalyzed Demercuration Reactions of Bis(alkynyl)mercurials
Chem. Commun. 2008, 497–498. [pdf]



Chem. Eur. J.

[140]

H. Braunschweig, M. Groß, K. Hammond, M. Friedrich, M. Kraft, A. Oechsner, K. Radacki, S. Stellwag
[2]Borametallocenophanes of Group 4 Metals: Synthesis and Structure
Chem. Eur. J. 2008, 14, 8972–8979. [pdf]

 

[139]

H. Braunschweig, K. Radacki, K. Uttinger
T-Shaped Platinum Boryl Complexes: Synthesis and Structure
Chem. Eur. J. 2008, 14, 7858–7866. [pdf]



Struct. Bond.

[138]

H. Braunschweig, C. Kollann, F. Seeler
Transition Metal Borylene Complexes
Struct. Bond. 2008, 130, 1–27. [pdf]



Inorg. Chem.

[137]

H. Braunschweig, K. Gruß, K. Radacki
The reactivity of Pt0 complexes towards gallium(III) halides: Synthesis of a platinum gallane complex and oxidative addition of gallium halides to Pt0
Inorg. Chem. 2008, 47, 8595–8597. [pdf]

 

[136]

H. Braunschweig, M. Kaupp, C. Lambert, D. Nowak, K. Radacki, S. Schinzel, K. Uttinger
Synthesis and Structure of a Ferrocenyl Boron Dication
Inorg. Chem. 2008, 47, 7456–7458. [pdf]



Dalton Trans.

[135]

H. Braunschweig, H. Green, K. Radacki, K. Uttinger
Synthesis of η1-Borazine Complexes of Palladium and Platinum
Dalton Trans. 2008, 3531–3534. [pdf]

 

[134]

H. Bera, H. Braunschweig, R. Dörfler, K. Radacki
Synthesis of a Bimetallic Platinum-Tungsten Complex with a bridging μ-Diboranyl-oxycarbyne Moiety
Dalton Trans. 2008, 440–443. [pdf]



Organometallics

[133]

H. Braunschweig, F. Breher, M. Kaupp, M. Groß, T. Kupfer, D. Nied, K. Radacki, S. Schinzel
Synthesis, Crystal Structure, EPR and DFT studies and Redox Properties of [2]Tetramethyldisilacobaltocenophane
Organometallics 2008, 27, 6427–6433. [pdf]

 

[132]

C. E. Anderson, H. Braunschweig, R. D. Dewhurst
Borylene transfer from transition metal borylene complexes
Organometallics 2008, 27, 6381–6389. [pdf]

 

Highlighted in:

"Introduction to the Review by Anderson, Braunschweig, and Dewhurst in This Issue of Organometallics", D. Seyferth, Organometallics 2008, 27, 6379–6380. [pdf]

 

[131]

H. Braunschweig, K. Radacki, K. Uttinger
Syntheses and structures of mono- and dinuclear cationic base-stabilized platinum borylene complexes
Organometallics 2008, 27, 6005–6012. [pdf]

 

[130]

H. Braunschweig, R. Leech, D. Rais, K. Radacki, K. Uttinger
Conversion of trans-Bromoboryl Platinum Complexes into their cis-Analogs upon Treatment with Chelating Bisphosphines
Organometallics 2008, 27, 418–422. [pdf]



Eur. J. Inorg. Chem.

[129]

H. Braunschweig, K. Gruß, K. Radacki, K. Uttinger
Oxidative Addition of B–Br bonds to Pd0 – Synthesis and Structure of trans-Bromo(boryl)palladium Complexes
Eur. J. Inorg. Chem. 2008, 1462–1466. [pdf]



Z. anorg. allg. Chem.

[128]

H. Braunschweig, M. Burzler, R. Dewhurst, K. Radacki, F. Seeler
Dimanganese Bridging Borylene Complexes and their Reactions with Unsaturated Pd(0) Complexes – Syntheses, Structures and Calculated Properties
Z. anorg. allg. Chem. 2008, 1875–1879. [pdf]



Z. Naturforsch.

[127]

T. Auch, H. Braunschweig, K. Radacki, U. Siemeling, R. Sigritz, S. Stellwag
Synthesis and Crystal Structure of 1,3-Diphenyl-2-ferrocenyl-1,3,2-di-azabora-[3]-ferrocenophane
Z. Naturforsch. 2008, 63b, 920–922. [pdf]