Publications 2011

Angew. Chem.


H. Braunschweig, F. Güthlein
Transition-Metal-Catalyzed Synthesis of Diboranes(4)
Angew. Chem. 2011, 123, 12821–12824; [pdf] Angew. Chem. Int. Ed. 2011, 50, 12613–12616. [pdf]



J. Bauer, H. Braunschweig, K. Kraft, K. Radacki
Oxidative Addition of Boron Trifluoride to a Transition Metal
Angew. Chem. 2011, 123, 10641–10644; [pdf] Angew. Chem. Int. Ed. 2011, 50, 10457–10460. [pdf]



H. Braunschweig, Q. Ye, T. Kupfer, J. Wolf
Synthesis of 1-Aza-2-borabutatriene Rhodium Complexes by Thermal Borylene Transfer from [(OC)5Mo=BN(SiMe3)2]
Angew. Chem. 2011, 123, 9634–9638; [pdf] Angew. Chem. Int. Ed. 2011, 50, 9462–9466. [pdf]



H. Braunschweig, A. Damme, T. Kupfer
Unexpected Bonding Mode of the Diboran(4)yl Ligand: Combining the Boryl Motif with a Dative Pt–B Interaction
Angew. Chem. 2011, 123, 7317–7320; [pdf] Angew. Chem. Int. Ed. 2011, 50, 7179–7182. [pdf]



P. Bissinger, H. Braunschweig, K. Kraft, T. Kupfer
Trapping the Elusive Parent Borylene
Angew. Chem. 2011, 123, 4801–4804; [pdf] Angew. Chem. Int. Ed. 2011, 50, 4704–4707. [pdf]



K. Ansorg, H. Braunschweig, C.-W. Chiu, B. Engels, D. Gamon, M. Hügel, T. Kupfer, K. Radacki
The Pentaphenylborole-2,6-Lutidine Adduct: A System with Unusual Thermochromic and Photochromic Properties
Angew. Chem. 2011, 123, 2885–2888; [pdf] Angew. Chem. Int. Ed. 2011, 50, 2833–2836. [pdf]

J. Am. Chem. Soc.


P. Bissinger, H. Braunschweig, A. Damme, R. D. Dewhurst, T. Kupfer, K. Radacki, K. Wagner
Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C-H Bond
J. Am. Chem. Soc. 2011, 133, 19044–19047. [pdf]



M. M. Safont-Sempere, P. Osswald, M. Stolte, M. Grüne, M. Renz, M. Kaupp, K. Radacki, H. Braunschweig, F. Würthner
Impact of Molecular Flexibility on Binding Strength and Self-Sorting of Chiral π-Surfaces
J. Am. Chem. Soc. 2011, 133, 9580–9591. [pdf]



H. Braunschweig, M. Fuß, T. Kupfer, K. Radacki
Selective Dilithiation of [Ti(η5-C5H5)(η8-C8H8)] and Subsequent Conversion into Neutral and Cationic ansa-Complexes
J. Am. Chem. Soc. 2011, 133, 5780–5783. [pdf]

Chem. Commun


J. Bauer, H. Braunschweig, A. Damme, K. Gruß, K. Radacki
Extending unsupported metal-only Lewis pairs to palladium
Chem. Commun. 2011, 47, 12783–12785. [pdf]



H. Braunschweig, T. Kupfer
Recent developments in the chemistry of antiaromatic boroles
Chem. Commun. 2011, 47, 10903–10914. [pdf]



H. Braunschweig, R. D. Dewhurst, K. Kraft, K. Radacki
Borido complexes via intermetallic metalloborylene transfer
Chem. Commun. 2011, 47, 9900–9902. [pdf]



H. Braunschweig, M. Friedrich, T. Kupfer, K. Radacki
Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers
Chem. Commun. 2011, 47, 3998–4000. [pdf]

Chem. Eur. J.


H. Braunschweig, R. Dörfler, J. Mies, A. Oechsner
Sterically Demanding Hetero-Substituted [2]Borametallocenophanes of Group IV Metals: Synthesis, Structure and Reactivity
Chem. Eur. J. 2011, 17, 12101–12107. [pdf]



H. Braunschweig, R. Bertermann, P. Brenner, M. Burzler, R. D. Dewhurst, K. Radacki, F. Seeler
trans-[Pt(BCat')Me(PCy3)2]: An Experimental Case Study of Reductive Elimination Processes in Pt-Boryls through Associative Mechanisms
Chem. Eur. J. 2011, 17, 11828–11837 (VIP). [pdf]



C. J. Adams, H. Braunschweig, M. Fuß, K. Kraft, T. Kupfer, I. Manners, K. Radacki, G. R. Whittell
Syntheses of Group 4 ansa-Trovacene Complexes and Conversion of [1]Silatrovacenophanes into Paramagnetic Metallopolymers by Ring-Opening Polymerization
Chem. Eur. J. 2011, 17, 10379–10387. [pdf]



F. Bauer, H. Braunschweig, K. Gruß, C. Lambert, K. K. Pandey, K. Radacki, D. Reitzenstein
Unexpected Generation of Diastereomers by Double Diboration of a Dialkyne
Chem. Eur. J. 2011, 17, 5230–5233. [pdf]



H. Braunschweig, S. Ghosh, T. Kupfer, K. Radacki, J. Wahler
High Yield Synthesis of a Hybrid 2,3,4,5-Tetracarba-1,6-nido-hexaborane(6) Cluster with an exo-Polyhedral Boracycle
Chem. Eur. J. 2011, 17, 4081–4084. [pdf]

Coord. Chem. Rev.


H. Braunschweig, P. Cogswell, K. Schwab
Synthesis, structure and reactivity of complexes containing a transition metal-bismuth bond
Coord. Chem. Rev. 2011, 255, 101–117. [link]

Inorg. Chem.


H. Braunschweig, A. Damme, D. Gamon, T. Kupfer, K. Radacki
Synthesis and Coordination Chemistry of 1-Cymantrenyl-2,3,4,5-tetraphenylborole
Inorg. Chem. 2011, 50, 4250–4252. [pdf]



H. Braunschweig, C.-W. Chiu, T. Kupfer, K. Radacki
NHC-Stabilized 1-Hydro-1H-borole and Its Nondegenerate Sigmatropic Isomers
Inorg. Chem. 2011, 50, 4247–4249. [pdf]



S. Bertsch, H. Braunschweig, M. Forster, K. Gruß, K. Radacki
Carbonyl Complexes of Platinum(0): Synthesis and Structure of [(Cy3P)2Pt(CO)] and [(Cy3P)2Pt(CO)2]
Inorg. Chem. 2011, 50, 1816–1819. [pdf]



K. K. Pandey, H. Braunschweig, A. Lledós
Nature of Bonding in Terminal Borylene, Alylene, and Gallylene complexes of Vanadium and Niobium [(η5-C5H5)(CO)3M(ENR2)] (M = V, Nb; E = B, Al, Ga; R = CH3, SiH3, CMe3, SiMe3): A DFT Study
Inorg. Chem. 2011, 50, 1402–1410. [pdf]



H. Braunschweig, P. Brenner, Q. Ye, K. Radacki, G. Frenking, S. De
Borylene-based Functionalization of Iron-Alkynyl-σ-Complexes and Stepwise Reversible Metal-Boryl-to-Borirene Transformation: Synthesis, Characterization, and Density Functional Theory Studies
Inorg. Chem. 2011, 50, 62–71. [pdf]

Dalton Trans.


H. Braunschweig, Q. Ye, K. Radacki, T. Kupfer
Reactivity of a platinum-substituted borirene
Dalton Trans. 2011, 40, 3666–3670. [pdf]



H. Braunschweig, R. D. Dewhurst
Transition metals as Lewis bases: "Z-type" boron ligands and metal-to-boron dative bonding
Dalton Trans. 2011, 40, 549–558. [pdf]



H. Braunschweig, M. Drisch, M. Friedrich, T. Kupfer, K. Radacki
Metal-Enriched [3]Trochrocenophanes: Bimetallic Metalloarenophanes by Coordination to Chelating Bis(phosphanyls)
Organometallics 2011, 30, 5202–5207. [pdf]



H. Braunschweig, C.-W. Chiu, A. Damme, K. Ferkinghoff, K. Kraft, K. Radacki, J. Wahler
Unwinding Antiaromaticity in 1-Bromo-2,3,4,5-tetraphenylborole
Organometallics 2011, 30, 3210–3216. [pdf]



F. Bauer, H. Braunschweig, K. Gruß, T. Kupfer
Diboration of Dialkynes with [2]Boraferrocenophanes
Organometallics 2011, 30, 2869–2884. [pdf]



H. Braunschweig, R. Dörfler, K. Gruß, J. Köhler, K. Radacki
Insertion vs Ligand Exchange: Reactivity of Distanna Ansa Half-Sandwich Complexes of Molybdenum and Tungsten toward Isocyanide and Phosphine Complexes of Nickel and Palladium
Organometallics 2011, 30, 305–312. [pdf]

Eur. J. Inorg. Chem.


K. K. Pandey, H. Braunschweig, R. D. Dewhurst
DFT Study on Alkyl- and Haloborylene Complexes of Manganese and Rhenium: Structure and Bonding Energy Analysis in [(η5-C5H5)(CO)2M(BR)] and [(η5-C5H5)(CO)2M(BX)] (M = Mn, Re; R = Me, Et, iPr, tBu; X = F, Cl, Br, I)
Eur. J. Inorg. Chem. 2011, 2045–2056. [pdf]

J. Organomet. Chem.


H. Braunschweig, M. Groß, K. Kraft
Synthesis and reactivity of [2]disilaniobocenophanes
J. Organomet. Chem. 2011, 696, 568–571. [pdf]

Z. anorg. allg. Chem.


H. Braunschweig, R. Dörfler, M. Friedrich, M. Kraft, A. Oechsner
Catalytic Activity of [2]Borametallocenophanes
Z. Anorg. Allg. Chem. 2011, 637, 2125–2128. [pdf]



H. Braunschweig, R. Dörfler, K. Gruß, K. Radacki
Synthesis and Reactivity of a Dilithiated Molybdenum Half-Sandwich Complex
Z. Anorg. Allg. Chem. 2011, 637, 381–385. [pdf]

Z. Naturforsch.


H. Braunschweig, K. Gruß
Synthesis and structural characterization of the dinuclear Beryllium species [Be2Cl2(μ-Cl)2(PCy3)2]
Z. Naturforsch. 2011, 66b, 55–57. [pdf]

Acta Cryst.


T. Arnold, H. Braunschweig, K. Gruß
cyclo-Tri-μ-oxido-tris{[η55)-1,2-bis(cyclopentadienyl)-1,1,2,2-tertramethyldisilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene
Acta Cryst. 2011, E67, m391. [pdf]

J. Phys. Chem.


J. Pfister, C. Schon, W. Roth, C. Kaiser, C. Lambert, K. Gruß, H. Braunschweig, I. Fischer, R. F. Fink, B. Engels
Paracyclophanes as Model Compounds for Strongly Interacting π-Systems, Part 3: Influence of the Substitution Pattern on Photoabsorption Properties
J. Phys. Chem. 2011, 115, 3583–3591. [pdf]

Polym. Prepr.


H. Braunschweig
Non-iron [n]Metalloarenophanes-Synthesis, Structure and Reactivity
Polym. Prepr. 2011, 52, 867.

ACS Meeting


H. Braunschweig
Non-iron [n]metalloarenophanes
ABSTR PAP AM CHEM S: 242nd ACS Meeting, POLY-550, 28 AUG - 01 SEP 11, 2011.