Publications 1990-2004



Angew. Chem.

[63]

H. Braunschweig, M. Colling, C. Hu, K. Radacki
[(η5-C5H5)(OC)3V=B=N(SiMe3)2]: A Half-Sandwich Complex with a Terminal Borylene Ligand
Angew. Chem. 2003, 115, 215–218; [pdf] Angew. Chem. Int. Ed. 2003, 42, 205–208. [pdf]

 

[62]

H. Braunschweig, M. Colling, C. Hu, K. Radacki
From Classical to Nonclassical Metal-Boron Bonds: Synthesis of a Novel Metallaborane
Angew. Chem. 2002, 114, 1415–1417; [pdf] Angew. Chem. Int. Ed. 2002, 41, 1359–1361. [pdf]

 

[61]

H. Braunschweig, M. Colling, C. Kollann, K. Merz, K. Radacki
[(OC)5Cr=BSi(SiMe3)3]: A Terminal Borylene Complex with an Electronically Unsaturated Boron Atom
Angew. Chem. 2001, 113, 4327–4329; [pdf] Angew. Chem. Int. Ed. 2001, 40, 4198–4200. [pdf]

 

[60]

H. Braunschweig, M. Colling, C. Kollann, B. Neumann, H.-G. Stammler
Terminal Borylene Complexes as a Source for the Borylene B–N(SiMe3)2: Alternative Synthesis and Structure of [(OC)5Cr=B=N(SiMe3)2]
Angew. Chem. 2001, 113, 2359–2361; [pdf] Angew. Chem. Int. Ed. 2001, 40, 2298–2300. [pdf]

 

[59]

H. Braunschweig, M. Koster, K. W. Klinkhammer
Unique Rearrangement of an Oxycarbyne Complex: Synthesis and Structure of Novel Diborane(4)yl Complexes
Angew. Chem. 1999, 111, 2368–2370; [pdf] Angew. Chem. Int. Ed. 1999, 38, 2229–2231. [pdf]

 

[58]

H. Braunschweig, C. Kollann, U. Englert
Synthesis and Structure of the First Terminal Borylene Complexes
Angew. Chem. 1998, 110, 3355–3357; [pdf] Angew. Chem. Int. Ed. 1998, 37, 3179–3180. [pdf]

 

Highlighted in:

 "Metal complexes bearing terminal borylene ligands", B. Wrackmeyer, Angew. Chem. Int. Ed. 1999, 38, 771–772. [pdf]

 

[57]

H. Braunschweig
Transition Metal Complexes of Boron
Angew. Chem. 1998, 110, 1882–1898; [pdf] Angew. Chem. Int. Ed. 1998, 37, 1786–1801. [pdf]

 

[56]

H. Braunschweig, R. Dirk, M. Müller, P. Nguyen, R. Resendes, D. P. Gates, I. Manners
Incorporation of a First Row Element into the Bridge of a Strained Metallacenophane: Synthesis of a Boron-Bridged [1]Ferrocenophane
Angew. Chem. 1997, 109, 2433–2435; [pdf] Angew. Chem. Int. Ed. 1997, 36, 2338–2340. [pdf]

 

[55]

H. Braunschweig, C. Drost, P. B. Hitchcock, M. F. Lappert, L. J.-M. Pierssens
A Dinuclear Tin(II) Amide, a meta-Stannylaminocyclophane and Its Orthostannylated Derivative, a Dimeric Trinuclear Tin(II) Cluster
Angew. Chem. 1997, 109, 285–288; [pdf] Angew. Chem. Int. Ed. 1997, 36, 261–263. [pdf]

 

[54]

H. Braunschweig, T. Wagner
Synthesis and Structure of the First Transition Metal Borylene Complexes
Angew. Chem. 1995, 107,904–905; [pdf] Angew. Chem. Int. Ed. 1995, 34, 825–826. [pdf]

 

[53]

H. Braunschweig, P. B. Hitchcock, M. F. Lappert, L. J.-M. Pierssens
Synthesis, Structures, and Reactions of Two Bis(diaminostannylene)s and a Bis(diaminogermylene) Containing a Central C6 Ring
Angew. Chem. 1994, 106, 1243–1245; [pdf] Angew. Chem. Int. Ed. 1994, 33, 1156–1158. [pdf]



J. Am. Chem. Soc.

[52]

H. Braunschweig, R. Dirk, U. Englert, F. Jäkle, A. Berenbaum, J. C. Green, A. J. Lough, I. Manners
Synthesis, Electronic Structure, and Novel Reactivity of Strained, Boron-Bridged [1]Ferrocenophanes
J. Am. Chem. Soc. 2000, 122, 5765–5774. [pdf]



Chem. Commun.

[51]

H. Braunschweig, G. D'Andola, T. Welton, A. J. P. White
Novel organocycloborates via Grignard reagents
Chem. Commun. 2004, 1738–1739. [pdf]

 

[50]

H. Braunschweig, C. von Koblinski, U. Englert
Synthesis and structure of the first boron bridged constrained geometry complexes
Chem. Commun. 2000, 1049–1050. [pdf]

 

[49]

H. Braunschweig, R. W. Chorley, P. B. Hitchcock, M. F. Lappert
The First Monomeric Prochiral Tin(II) Complexes Sn[N(SiMe3)2]X [X = OC6H2tBu2-2,6-Me-4, 1 or NCMe2(CH2)3CMe2, 2]; the X-Ray Structure of 1 and Oxidative Addition Reactions of 2
J. Chem. Soc., Chem. Commun. 1992, 1311–1313. [pdf]



Chem. Eur. J.

[48]

H. Braunschweig, K. W. Klinkhammer, M. Koster, K. Radacki
Formation, Structure and Reactivity of Boryloxycarbyne Complexes of Group 6 Metals
Chem. Eur. J. 2003, 9, 1303–1309. [pdf]



Coord. Chem. Rev.

[47]

H. Braunschweig, M. Colling
Transition metal complexes of boron - synthesis, structure and reactivity
Coord. Chem. Rev. 2001, 223, 1–51. [pdf]



Adv. Organomet. Chem.

[46]

H. Braunschweig
Borylenes as Ligands to Transition Metals
Adv. Organomet. Chem. 2004, 51, 163–192. [pdf]



Inorg. Chem.

[45]

H. Braunschweig, M. Colling, C. Hu
Unprecedented Reactivity of the Bridged Borylene Complex [μ-BCl{(η5-C5H4Me)Mn(CO)2}2] toward Pyridine
Inorg. Chem. 2003, 42, 941–943. [pdf]

 

[44]

H. Braunschweig, M. Koster, R. Wang
Diborane(4)yl Complexes of Molybdenum and Ruthenium
Inorg. Chem. 1999, 38, 415–416. [pdf]

 

[43]

H. Braunschweig, J. Müller, B. Ganter
Molecular Structure of [CpFe(CO)2]2AlAr (Ar = 2-[(Dimethylamino)methyl]phenyl): An Alanediyl Complex with Two Fe–Al Bonds
Inorg. Chem. 1996, 35, 7443–7444. [pdf]



Dalton Trans.

[42]

H. Braunschweig, F. M. Breitling, C. von Koblinski, A. J. P. White, D. J. Williams
Synthesis and structure of boron-bridged constrained geometry complexes of titanium
Dalton Trans. 2004, 938–943. [pdf]

 

[41]

H. Braunschweig, M. Colling, C. Kollann, U. Englert
The first silyl- and germylboryl complexes: synthesis from novel dichloro(silyl)- and dichloro(germyl)boranes, structure and reactivity
Dalton Trans. 2002, 2289–2296. [pdf]



Organometallics

[40]

H. Braunschweig, K. Radacki, D. Rais, F. Seeler
Preparation and Structural Characterization of Transition Metal Complexes Featuring the Ferrocenyl(bromo)boryl Ligand
Organometallics, 2004, 23, 5545–5549. [pdf]

 

[39]

H. Braunschweig, K. Radacki, F. Seeler, G. R. Whittell
Synthesis of [(η5-C5H5)Fe(CO)2BCl2·NC5H4-4-Me] from [(η5-C5H5)Fe(CO)2BCl2]: First Preparation of a Lewis Acid-Base Adduct from a Boryl Complex
Organometallics, 2004, 23, 4178–4180. [pdf]

 

[38]

H. Braunschweig, M. Homberger, C. Hu, X. Zheng, E. Gullo, G. Clentsmith, M. Lutz
Synthesis and Structure of [Cr{(η6-C6H5)2B{NtBu(SiMe3)}}] and [Cr{(η6-C6H5)2(BNMe2)2}], the First Boron-Bridged Metalloarenophanes
Organometallics, 2004, 23, 1968–1970. [pdf]



Eur. J. Inorg. Chem. / Chem. Ber.

[37]

H. Braunschweig, M. Colling
The Chemistry of Borylene Complexes
Eur. J. Inorg. Chem. 2003, 393–403. [pdf]

 

[36]

H. Braunschweig, C. Kollann, M. Koster, U. Englert, M. Müller
Synthesis and Structure of Trinuclear Boryloxycarbyne Complexes
Eur. J. Inorg. Chem. 1999, 2277–2281. [pdf]

 

[35]

H. Braunschweig, C. von Koblinski, M. Mamuti, U. Englert, R. Wang
Synthesis and Structure of [1]Borametallocenophanes of Titanium, Zirconium, and Hafnium
Eur. J. Inorg. Chem. 1999, 1899–1904. [pdf]

 

[34]

H. Braunschweig, C. Kollann, K. W. Klinkhammer
Boryl and Bridged Borylene Complexes of Iron and Ruthenium
Eur. J. Inorg. Chem. 1999, 1523–1529. [pdf]

 

[33]

H. Braunschweig, C. von Koblinski, R. Wang
Synthesis and Structure of the First [1]Boratitanocenophanes
Eur. J. Inorg. Chem. 1999, 69–73. [pdf]

 

[32]

H. Braunschweig, C. Kollann, U. Englert
Boryl- and Bridging Boryleneiron Complexes from Aminodichloroboranes
Eur. J. Inorg. Chem. 1998, 465–468. [pdf]

 

[31]

H. Braunschweig, C. Kollann, M. Müller
Synthesis and Structure of the First η1-Borazine Complexes
Eur. J. Inorg. Chem. 1998, 291–293. [pdf]

 

[30]

H. Braunschweig, M. Müller
New Borylene Complexes of the Type [μ-BX{(η5-C5H4Me)Mn(CO)2}2]; Substitution Reactions at the Metal- Coordinated Borylene Moiety
Chem. Ber. 1997, 130, 1295–1298. [pdf]

 

[29]

H. Braunschweig, B. Ganter, M. Koster, T. Wagner
Diboran(4)yl Groups as Ligands to Transition Metals
Chem. Ber. 1996, 129, 1099–1101. [pdf]

 

[28]

H. Braunschweig, T. Wagner
Zur Addition von Alkyldichlorboranen an Bis(η5-cyclopentadienyl)dihydridowolfram
Chem. Ber. 1994, 127, 1613–1614. [pdf]

 

[27]

H. Braunschweig, T. P. Spaniol, P. Paetzold
Zur Bildung eines Fe2(CO)6-Komplexes mit (Boryloxy)allyl-Brücke
Chem. Ber. 1994, 127, 91–92. [pdf]

 

[26]

H. Braunschweig, P. Paetzold, R. Boese
Weitere Reaktionen der Iminoborane RB≡NR′ mit Neopentylidentantal-Komplexen
Chem. Ber. 1993, 126, 1571–1577. [pdf]

 

[25]

H. Braunschweig, P. Paetzold, T. P. Spaniol
Weitere Reaktionen des Amino(imino)borans Me3Si(tBu)N–B=NtBu und des Alkyliden(amino)borans Me3Si(tBu)N=B=CHtBu
Chem. Ber. 1993, 126, 1565–1569. [pdf]

 

[24]

H. Braunschweig, P. Paetzold, R. Boese
[2 + 2]-Cycloaddition von Iminoboranen mit einem Neopentylidentantal-Komplex
Chem. Ber. 1990, 123, 485–487. [pdf]



J. Organomet. Chem.

[23]

H. Braunschweig, F. M. Breitling, E. Gullo, M. Kraft
The chemistry of [1]borametallocenphanes and related compounds
J. Organomet. Chem. 2003, 680, 31–42. [pdf]

 

[22]

H. Braunschweig, C. von Koblinski C., M. Neugebauer, U. Englert, X. Zheng
Synthesis and structure of aminobis(η1-cyclopentadienyl)boranes and related compounds
J. Organomet. Chem. 2001, 619, 305–312. [pdf]

 

[21]

H. Braunschweig, M. Colling
The chemistry of bridged borylene complexes
J. Organomet. Chem. 2000, 614–615, 18–26. [pdf]

 

[20]

H. Braunschweig, M. Koster
Diborane(4)yl and bridged borylene complexes from 1,2-dipyrrolidino- and 1,2-dipiperidinodiborane(4) derivatives
J. Organomet. Chem. 1999, 588, 231–234. [pdf]

 

[19]

H. Braunschweig, R. Dirk, B. Ganter
{[Bis(dimethylamino)boryl]methyl}dimethylphosphane as ligand in transition metal complexes
J. Organomet. Chem. 1997, 545, 257–266. [pdf]

 

[18]

H. Braunschweig, B. Ganter
Convenient synthesis of K[(C5H4Me)MnH(CO)2] and reactions with Cl2B[N(SiMe3)2] and B2R2Cl2 (R = Me2N, Me3C)
J. Organomet. Chem. 1997, 545, 163–167. [pdf]



Inorg. Chim. Acta

[17]

H. Braunschweig, M. Colling, C. Hu, K. Radacki
Reactivity of the bridged borylene complex [μ-BCl{(η5-C5H4Me)Mn(CO)2}2]
Inorg. Chim. Acta, 2004, 357, 1822–1828. [pdf]

 

[16]

H. Braunschweig, C. von Koblinski, F. M. Breitling, K. Radacki, C. Hu, L. Wesemann, T. Marx, I. Pantenburg
Synthesis and structure of [Zr{η51-C9H6B(NiPr2)NPh}2]: a new complex with a boron-bridged amido-indenyl ligand
Inorg. Chim. Acta, 2003, 350, 467–474. [pdf]



Z. anorg. allg Chem.

[15]

H. Braunschweig, F. M. Breitling, M. Homberger, C. von Koblinski, A. J. P. White, D. J. Williams
Cyclopentadienyl(diamino)boranes and their Derivatives - a Family of Versatile Ligand Precursors for Constrained Geometry Complexes
Z. anorg. allg. Chem. 2003, 629, 2244–2250. [pdf]

 

[14]

H. Braunschweig, R. Dirk, U. Englert
Synthesis and Reactions of an {o-{[Bis(dimethylamino)boryl]methyl}phenyl}diphenylphosphane
Z. anorg. allg. Chem. 1997, 623, 1093–1097. [pdf]

 

[13]

H. Braunschweig, B. Gerhus, P. B. Hitchcock, M. F. Lappert
Synthesis and Characterisation of N,N′-Disubstituted 1,2-phenylenebis(amido)tin(II) Compounds; X-Ray Structures of 1,2-C6H4[N(CH2But)]2Sn and of [1,2-C6H4{N(SiMe3)}2Sn]2Sn(tmeda)
Z. anorg. allg. Chem. 1995, 621, 1922–1928. [pdf]



Z. Naturforsch.

[12]

H. Braunschweig, M. Koster
Synthesis and Reactivity of Diborane(4)yl Complexes
Z. Naturforsch. 2002, 57b, 483–487. [pdf]

 

[11]

H. Braunschweig, C. Kollann
Reaktionen von [(η5-C5R5)2WH2] mit Boranen
Z. Naturforsch. 1999, 54b, 839–842. [pdf]

 

[10]

H. Braunschweig, T. Wagner
Zur Umsetzung von Bis(η5-cyclopentadienyl)dihydridowolfram mit Halogenboranen
Z. Naturforsch. 1996, 51b, 1618–1620. [pdf]

 

[9]

H. Braunschweig, I. Manners, P. Paetzold
Die Reaktion von (Butadien)zirconocen mit Iminoboranen
Z. Naturforsch. 1990, 45b, 1453–1454. [pdf]



Appl. Organomet. Chem.

[8]

H. Braunschweig, M. Kraft, M. Homberger, F. M. Breitling, A. J. P. White, U. Englert, D. J. Williams
Synthesis and structures of [Yb{η5-(C5H4)B(NiPr2)NHtBu}2{N(SiMe3)2}] and [Zr{η5-(C9H6)B(N(SiMe3)2)(C9H7)}Cl2]
Appl. Organomet. Chem. 2003, 17, 421–428. [pdf]



Phosphorus, Sulfur, Silicon Relat. Elem.

[7]

D. P. Gates, R. Rulkens, R. Dirk, P. Nguyen, J. K. Pudelski, R. Resendes, H. Braunschweig, I. Manners
Highly Strained Metallocenophanes: Synthesis and Ring-Opening of Sulfur-, Selenium- and Boron-Bridged [1]Ferrocenophanes
Phosphorus, Sulfur Silicon Relat. Elem. 1997, 124 & 125, 561–565. [pdf]



The Royal Society of Chemistry

[6]

H. Braunschweig
in: Contemporary Boron Chemistry (Eds.: M. G. Davidson, A. K. Hughes, T. B. Marder, K. Wade),
The Royal Society of Chemistry, Cambridge, 2000, pp. 371–378.

 

[5]

H. Braunschweig
in: Advances in Boron Chemistry (Ed.: W. Siebert),
The Royal Society of Chemistry, Cambridge, 1997, pp. 381–384.



Wiley-VCH

[4]

H. Braunschweig
in: Inorganic Chemistry Highlights (Eds.: G. Meyer, D. Naumann, L. Wesemann),
Wiley-VCH, Weinheim, New York, 2001, 213–218.



ACS Meetings

[3]

H. Braunschweig, G. D'Andola, T. Welton
Synthesis and characterization of novel organoborates via Grignards reagents
ABSTR PAP AM CHEM S: 228th ACS Meeting, INOR-541, 22 AUG 04, 2004.

 

[2]

A. Berenbaum, H. Braunschweig, R. Dirk, U. Englert, J. C. Green, F. Jäkle, I. Manners
Synthesis, electronic structure, and novel reactivity of strained, boron-bridged [1]ferrocenophanes
ABSTR PAP AM CHEM S: 221st ACS Meeting, INOR-358, 01 APR 01, 2001.



Patent

[1]

H. Braunschweig, C. von Koblinski, M. O. Kristen
METALLOCENE COMPLEXES
EP 1140955 (A1), 2001. [link]