Publications 2020
Nature Chem.
|
[584] |
M.-A. Légaré, G. Bélanger-Chabot, M. Rang, R. D. Dewhurst, I. Krummenacher, R. Bertermann, H. Braunschweig
One-pot, room-temperature conversion of dinitrogen to ammonium chloride at a main-group element
|
Angew. Chem.
|
[583] |
C. Saalfrank, F. Fantuzzi, T. Kupfer, B. Ritschel, K. Hammond, I. Krummenacher, R. Bertermann, R. Wirthensohn, M. Finze, P. Schmid, V. Engel, B. Engels, H. Braunschweig cAAC-Stabilized 9,10-diboraanthracenes – Acenes with Open-Shell Singlet Biradical Ground States (VIP) Angew. Chem. 2020, 132, 19502–19507; [pdf] Angew. Chem. Int. Ed. 2020, 59, 19338–19343. [pdf]
|
|
[582] |
S. Nees, T. Kupfer, A. Hofmann, H. Braunschweig Planar Cyclopenten-4-yl Cations – Highly Delocalized π Aromatics Stabilized by Hyperconjugation Angew. Chem. 2020, 132, 18971–18978; [pdf] Angew. Chem. Int. Ed. 2020, 59, 18809–18815. [pdf]
|
|
[581] |
A. Hermann, F. Fantuzzi, M. Arrowsmith, T. Zorn, I. Krummenacher, B. Ritschel, K. Radacki, B. Engels, H. Braunschweig Oxidation, Coordination and Nickel-Mediated Deconstruction of a Highly Electron-Rich Diboron Analogue of 1,3,5-Hexatriene Angew. Chem. 2020, 132, 15847–15855; [pdf] Angew. Chem. Int. Ed. 2020, 59, 15717–15725. [pdf]
|
|
[580] |
T. Thiess, G. Bélanger-Chabot, F. Fantuzzi, M. Michel, M. Ernst, B. Engels, H. Braunschweig Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes Angew. Chem. 2020, 132, 15608–15614; [pdf] Angew. Chem. Int. Ed. 2020, 59, 15480–15486. [pdf]
|
|
[579] |
V. Paprocki, P. Hrobárik, K. L. M. Harriman, M. S. Luff, T. Kupfer, M. Kaupp, M. Murugesu, H. Braunschweig Stable Actinide π Complexes of a Neutral 1,4-Diborabenzene Angew. Chem. 2020, 132, 13209–13216; [pdf] Angew. Chem. Int. Ed. 2020, 59, 13109–13115. [pdf]
|
|
[578] |
Z. Huang, S. Wang, R. D. Dewhurst, N. V. Ignat'ev, M. Finze, H. Braunschweig Boron: Its Role in Energy-Related Processes and Applications Angew. Chem. 2020, 132, 8882–8900; [pdf] Angew. Chem. Int. Ed. 2020, 59, 8800–8816. [pdf]
|
|
[577] |
J. H. Müssig, P. Lisinetskaya, R. D. Dewhurst, R. Bertermann, M. Thaler, R. Mitrić, H. Braunschweig Tetraiododiborane(4) (B2I4) is an Polymer based on sp3 Boron in the Solid State Angew. Chem. 2020, 132, 5574–5579; [pdf] Angew. Chem. Int. Ed. 2020, 59, 5531–5535. [pdf]
|
|
[576] |
U. Schmidt, L. Werner, M. Arrowsmith, A. Deißenberger, A. Hermann, A. Hofmann, S. Ullrich, J. D. Mattock, A. Vargas, H. Braunschweig Trans-selective Insertional Dihydroboration of a cis-Diborene: Synthesis of Linear sp3-sp2-sp3-Triboranes and Subsequent Cationization Angew. Chem. 2020, 132, 333–337; [pdf] Angew. Chem. Int. Ed. 2020, 59, 325–329. [pdf] |
J. Am. Chem. Soc.
|
[575] |
Y.-M. Tian, X.-N. Guo, I. Krummenacher, Z. Wu, J. Nitsch, H. Braunschweig, U. Radius, T. B. Marder
Visible-Light-Induced Ni-Catalyzed Radical Borylation of Chloroarenes
|
|
[574] |
Y.-M. Tian, X.-N. Guo, Z. Wu, A. Friedrich, S. A. Westcott, H. Braunschweig, U. Radius, T. B. Marder
Ni-Catalyzed Traceless, Directed C3-Selective C-H Borylation of Indoles
|
|
[573] |
A. Hermann, M. Arrowsmith, D. E. Trujillo-Gonzalez, J. O. C. Jiménez-Halla, A. Vargas, H. Braunschweig Trapping of a Borirane Intermediate in the Reductive Coupling of an Arylborane to a Diborene J. Am. Chem. Soc. 2020, 142, 5562–5567. [pdf]
|
|
[572] |
D. Prieschl, G. Bélanger-Chabot, X. Guo, M. Dietz, M. Müller, I. Krummenacher, Z. Lin, H. Braunschweig Synthesis of Complex Boron-Nitrogen Heterocycles Comprising Borylated Triazenes and Tetrazenes Under Mild Conditions J. Am. Chem. Soc. 2020, 142, 1065–1076. [pdf] |
Chem. Sci.
|
[571] |
C. Pranckevicius, M. Weber, I. Krummenacher, A. K. Phukan, H. Braunschweig Phosphinoborylenes as stable sources of fleeting borylenes Chem. Sci. 2020, 11, 11055–11059. [pdf]
|
|
[570] |
M. W. Kuntze-Fechner, H. Verplancke, L. Tendera, M. Diefenbach, I. Krummenacher, H. Braunschweig, T. B. Marder, M. C. Holthausen, U. Radius Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene Chem. Sci. 2020, 11, 11009–11023. [pdf]
|
|
[569] |
M. Heß, T. E. Stennett, F. Fantuzzi, R. Bertermann, M. Schock, M. Schäfer, T. Thiess, H. Braunschweig Diverse ring-opening reactions of rhodium η4-azaborete complexes Chem. Sci. 2020, 11, 9134–9140. [pdf]
|
|
[568] |
R. Drescher, S. Lin, A. Hofmann, C. Lenczyk, S. Kachel, I. Krummenacher, Z. Lin, H. Braunschweig Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum-nitrogen heterocycles Chem. Sci. 2020, 11, 5559–5564. [pdf]
|
|
[567] |
T. E. Stennett, A. Jayaraman, T. Brückner, L. Schneider, H. Braunschweig Hydrophosphination of boron-boron multiple bonds Chem. Sci. 2020, 11, 1335–1341. [pdf]
|
|
[566] |
S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Hermann, V. Paprocki, R. Drescher, I. Krummenacher, H. Braunschweig Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling Chem. Sci. 2020, 11, 551–555. [pdf] |
Chem. Eur. J.
|
[565] |
A. Rempel, S. K. Mellerup, F. Fantuzzi, A. Herzog, A. Deißenberger, R. Bertermann, B. Engels, H. Braunschweig
Functionalization of N2 via Formal 1,3-Haloboration of a Tungsten(0) σ-Dinitrogen Complex
|
|
[564] |
F. Rauch, P. Endres, A. Friedrich, D. Sieh, M. Hähnel, I. Krummenacher, H. Braunschweig, M. Finze, L. Ji, T. B. Marder
An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers
|
|
[563] |
F. Rauch, S. Fuchs, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder
Highly Stable, Readily Reducible, Fluorescent, Trifluoromethylated 9-Borafluorenes (VIP)
|
|
[562] |
J. Merz, L. Dietrich, J. Nitsch, I. Krummenacher, H. Braunschweig, M. Moos, D. Mims, C. Lambert, T. B. Marder
Synthesis, Photophysical and Electronic Properties of Mono-, Di-, Tri- and Tetra-Amino-Substituted Ortho-Perylenes, and Comparison to the
Tetra-Substituted Derivative
|
|
[561] |
F. Rauch, J. Krebs, J. Günther, A. Friedrich, M. Hähnel, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder
Electronically-Driven Regioselective Iridium-Catalyzed C-H Borylation of Donor- π-Acceptor Chromophores Containing Triarylboron Acceptors
|
|
[560] |
C. Brunecker, J. H. Müssig, M. Arrowsmith, F. Fantuzzi, A. Stoy, J. Böhnke, A. Hofmann, R. Bertermann, B. Engels, H. Braunschweig Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes Chem. Eur. J. 2020, 26, 8518–8523. [pdf]
|
|
[559] |
T. Thiess, M. Ernst, T. Kupfer, H. Braunschweig Facile Access to Substituted 1,4-Diaza-2,3-Diborinines Chem. Eur. J. 2020, 26, 2967–2972. [pdf]
|
|
[558] |
J. T. Goettel, H. Gao, S. Dotzauer, H. Braunschweig MeCAAC=N−: A Cyclic (Alkyl)(Amino)Carbene Imino Ligand Chem. Eur. J. 2020, 26, 1136–1143. [pdf]
|
|
[557] |
J. Merz, M. Dietz, Y. Vonhausen, F. Wöber, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Moos, M. Holzapfel, C. Lambert, T. B. Marder Synthesis, Photophysical and Electronic Properties of New Red-to-NIR Emitting Donor-Acceptor Pyrene Derivatives Chem. Eur. J. 2020, 26, 438–453. [pdf] |
Chem. Commun.
|
[556] |
U. Schmidt, F. Fantuzzi, M. Arrowmsith, A. Hermann, D. Prieschl, A. Rempel, B. Engels, H. Braunschweig Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes Chem. Commun. 2020, 56, 14809–14812. [pdf]
|
|
[555] |
S. Liu, M.-A. Légaré, T. Dellermann, A. Hofmann, H. Braunschweig Transition-metal-carbene-like intermolecular insertion of a borylene into C-H bonds Chem. Commun. 2020, 56, 7277–7280. [pdf]
|
|
[554] |
D. Prieschl, M. Arrowsmith, M. Dietz, A. Rempel, M. Müller, H. Braunschweig Synthesis of polyheterocyclic 1,1-diboryltriazenes by γ-nitrogen insertion of azides into activated B-B single bonds Chem. Commun. 2020, 56, 5681–5684. [pdf] |
Commun. Chem.
|
[553] |
R. D. Dewhurst, M.-A. Légaré, H. Braunschweig
Towards the catalytic activation of inert small molecules by main-group ambiphiles |
Inorg. Chem.
|
[552] |
S. Liu, M.-A. Légaré, J. Seufert, D. Prieschl, A. Rempel, L. Englert, T. Dellermann, V. Paprocki, A. Stoy, H. Braunschweig
2,2'-Bipyridyl as a Redox-Active Borylene Abstraction Agent |
Dalton Trans.
|
[551] |
B. Macha, D. Dhara, K. Radacki, R. D. Dewhurst, H. Braunschweig
Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal
borylene complex and other rare species |
Adv. Funct. Mater.
|
[550] |
A. Narsaria, F. Rauch, J. Krebs, P. Endres, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Finze, J. Nitsch, F. M. Bickelhaupt, T. B. Marder
Computationally Guided Molecular Design to Minimize the LE/CT Gap in D-π-A
Fluorinated Triarylboranes for Efficient TADF via D and π-Bridge Tuning |
J. Catal.
|
[549] |
Z.-F. Jiao, Y.-M. Tian, B. Zhang, C.-H. Hao, Y. Qiao, Y.-X. Wang, Y. Qin, U. Radius, H. Braunschweig, T. B. Marder, X.-N. Guo, X.-Y. Guo High photocatalytic activity of a NiO nanodot-decorated Pd/SiC Catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and chlorides in air under visible light J. Catal. 2020, 389, 517–524. [link] |
Eur. J. Inorg. Chem.
|
[548] |
G. Horrer, M. J. Krahfuß, K. Lubitz, I. Krummenacher, H. Braunschweig, U. Radius N-Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Complexes of Titanium(IV) and Titanium(III) Eur. J. Inorg. Chem. 2020, 281–291. [pdf] |
Chem. Asian J.
|
[547] |
W. C. Ewing, T. Dellermann, Y. T. A. Wong, J. D. Mattock, A. Vargas, D. L. Bryce, R. D. Dewhurst, H. Braunschweig π-Complexes of Diborynes and Main Group Atoms Chem. Asian J. 2020, 15, 1553–1557. [pdf] |
Chemie in unserer Zeit
|
[546] |
M. Rang, H. Braunschweig Die Verkettung zweier Stickstoffmoleküle Chem. Unserer Zeit 2020, 54, 8–9. [pdf] |
Book contributions
|
[545] |
I. Krummenacher, J. K. Schuster, H. Braunschweig
Synthesis and Reactivity of Bora- and Boratabenzenes |