Publications 2014



Angew. Chem.

[358]

Y.-L. Rao, C. Hörl, H. Braunschweig, S. Wang
Reversible Photochemical and Thermal Isomerization of Azaboratabisnorcaradiene to Azaborabenzotropilidene
Angew. Chem. 2014, 126, 9232–9236; [pdf] Angew. Chem. Int. Ed. 2014, 53, 9086–9089. [pdf]

 

[357]

J. Böhnke, H. Braunschweig, W. C. Ewing, C. Hörl, T. Kramer, I. Kummenacher, J. Mies, A. Vargas
Diborabutatriene: An Electron-Deficient Cumulene
Angew. Chem. 2014, 126, 9228–9231; [pdf] Angew. Chem. Int. Ed. 2014, 53, 9082–9085. [pdf]

 

Highlighted in:

"Trendberichte 2014: Anorganische Molekülchemie", S. Inoue, T. Böttcher, Nachrichten aus der Chemie 2015, 63, 228. [link]

 

[356]

P. Bissinger, H. Braunschweig, A. Damme, I. Krummenacher, A. K. Phukan, K. Radacki, S. Sugawara
Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene
Angew. Chem. 2014, 126, 7488–7491; [pdf] Angew. Chem. Int. Ed. 2014, 53, 7360–7363. [pdf]

 

Highlighted in:

"Trendberichte 2014: Anorganische Molekülchemie", S. Inoue, T. Böttcher, Nachrichten aus der Chemie 2015, 63, 228. [link]

 

[355]

H. Braunschweig, R. D. Dewhurst, K. Radacki, C. W. Tate, A. Vargas
Trihapto Ligation of a Borirene to a Single Metal Atom: a Heterocyclic Analogue of the η3-Cyclopropenyl Ligand
Angew. Chem. 2014, 126, 6378–6381; [pdf] Angew. Chem. Int. Ed. 2014, 53, 6263–6266. [pdf]

 

[354]

H. Braunschweig, P. Bissinger, A. Damme, T. Kupfer, I. Krummenacher, A. Vargas
Boron Radical Cations from the Facile Oxidation of Electron-Rich Diborenes
Angew. Chem. 2014, 126, 5797–5801; [pdf] Angew. Chem. Int. Ed. 2014, 53, 5689–5693. [pdf]

 

Highlighted in:

"Trendberichte 2014: Anorganische Molekülchemie", S. Inoue, T. Böttcher, Nachrichten aus der Chemie 2015, 63, 228. [link]

 

[353]

R. Bertermann, H. Braunschweig, R. D. Dewhurst, C. Hörl, T. Kramer, I. Krummenacher
Evidence for Extensive Single-Electron-Transfer Chemistry in Boryl Anions: Isolation and Reactivity of a Neutral Borole Radical
Angew. Chem. 2014, 126, 5557–5561; [pdf] Angew. Chem. Int. Ed. 2014, 53, 5453–5457. [pdf]

 

Highlighted in:

"Trendberichte 2014: Anorganische Molekülchemie", S. Inoue, T. Böttcher, Nachrichten aus der Chemie 2015, 63, 230. [link]

 

[352]

S. Bertsch, R. Bertermann, H. Braunschweig, A. Damme, R. D. Dewhurst, A. K. Phukan, C. Saalfrank, A. Vargas, B. Wennemann, Q. Ye
Metal-Only Lewis Pairs by Reversible Insertion of Ruthenium and Osmium Fragments into Metal-Boron Double Bonds
Angew. Chem. 2014, 126, 4326–4329; [pdf] Angew. Chem. Int. Ed. 2014, 53, 4240–4243. [pdf]

 

Highlighted in:

"Trendberichte 2014: Koordinationschemie", I. Siewert, M. D. Walter, Nachrichten aus der Chemie 2015, 63, 248. [link]

 

[351]

H. Braunschweig, K. Geetharani, J. O. C. Jimenez-Halla, M. Schäfer
Direct Synthetic Route to Functionalized 1,2-Azaborinines
Angew. Chem. 2014, 126, 3568–3572; [pdf] Angew. Chem. Int. Ed. 2014, 53, 3500–3504. [pdf]

 

[350]

H. Braunschweig, R. D. Dewhurst, C. Hörl, A. K. Phukan, F. Pinzner, S. Ullrich
Direct Hydroboration of B=B Bonds: A Mild Strategy for the Proliferation of B–B Bonds
Angew. Chem. 2014, 126, 3305–3308; [pdf] Angew. Chem. Int. Ed. 2014, 53, 3241–3244. [pdf]

 

Highlighted in:

"Trendberichte 2014: Anorganische Molekülchemie", S. Inoue, T. Böttcher, Nachrichten aus der Chemie 2015, 63, 228. [link]

 

[349]

J. Brand, H. Braunschweig, F. Hupp, A. K. Phukan, K. Radacki, S. S. Sen
A B–C Double Bond Unit Coordinated to Platinum: An Alkylideneboryl Ligand that is Isoelectronic to Neutral Aminoborylene Ligands
Angew. Chem. 2014, 126, 2273–2277; [pdf] Angew. Chem. Int. Ed. 2014, 53, 2240–2244. [pdf]



J. Am. Chem. Soc.

[348]

H. Braunschweig, Q. Ye, A. Vargas, R. D. Dewhurst, F. Hupp
Complete and Partial 1,2-Additions Across Transition Metal-Boron Double Bonds
J. Am. Chem. Soc. 2014, 136, 9560–9563. [pdf]



Chem. Sci.

[347]

H. Braunschweig, R. D. Dewhurst, F. Hupp, C. Kaufmann, A. K. Phukan, C. Schneider, Q. Ye
Gauging metal Lewis basicity of zerovalent iron complexes via metal-only Lewis pairs
Chem. Sci. 2014, 5, 4099–4104. [pdf]

 

[346]

H. Braunschweig, T. Kramer, K. Radacki, R. Shang, E. Siedler, C. Werner
Isolation of the key intermediates of base-promoted borylene-carbonyl coupling reactions
Chem. Sci. 2014, 5, 2271–2276. [pdf]



Chem. Commun.

[345]

H. Braunschweig, R. D. Dewhurst, F. Hupp, C. Schneider
Silver(I) and thallium(I) cations as unsupported bridges between two metal bases
Chem. Commun. 2014, 50, 15685–15688. [pdf]

 

[344]

H. Braunschweig, C. Hörl
Unexpected cluster formation upon hydroboration of a neutral diborene with 9-BBN
Chem. Commun. 2014, 50, 10983–10985. [pdf]

 

[343]

R. Bertermann, H. Braunschweig, W. C. Ewing, T. Kramer, A. K. Phukan, A. Vargas, C. Werner
Synthesis and characterization of a mercury-containing trimetalloboride
Chem. Commun. 2014, 50, 5729–5732. [pdf]

 

[342]

R. Bertermann, H. Braunschweig, C. K. L. Brown, A. Damme, R. D. Dewhurst, C. Hörl, T. Kramer, I. Krummenacher, B. Pfaffinger, K. Radacki
Diverse reactions of N-heterocyclic carbenes with an alkynylborane and isolation of a reactive zwitterionic borataallene
Chem. Commun. 2014, 50, 97–99. [pdf]



Chem. Eur. J.

[341]

F. Hupp, M. Ma, F. Kroll, J. O. C. Jimenez-Halla, R. D. Dewhurst, K. Radacki, A. Stasch, C. Jones, H. Braunschweig
Platinum Complexes Containing Pyramidalized Germanium and Tin Dihalide Ligands Bound through σ,σ M=E Multiple Bonds
Chem. Eur. J. 2014, 20, 16888–16898. [pdf]

 

[340]

H. Braunschweig, C. Hörl, L. Mailänder, K. Radacki, J. Wahler
Antiaromaticity to Aromaticity: From Boroles to 1,2-Azaborinines by Ring Expansion with Azides
Chem. Eur. J. 2014, 20, 9858–9861. [pdf]

 

Highlighted in:

"A New Route to Azaborinines", H. Charville, ChemViews Magazine 2014. [link]

 

[339]

F. Holzmeier, M. Lang, P. Hemberger, A. Bodi, M. Schäfer, R. D. Dewhurst, H. Braunschweig, I. Fischer
Photoionization and Pyrolysis of a 1,4-Azaborinine: Retro-Hydroboration in the Cation and Identification of Novel Organoboron Ring Systems
Chem. Eur. J. 2014, 20, 9683–9692. [pdf]

 

[338]

H. Braunschweig, C. K. L. Brown, R. D. Dewhurst, J. O. C. Jimenez-Halla, T. Kramer, I. Krummenacher, B. Pfaffinger
Boryl-Functionalized σ-Alkynyl and Vinylidene Rhodium Complexes: Synthesis and Electronic Properties
Chem. Eur. J. 2014, 20, 1427–1433. [pdf]



Acc. Chem. Res.

[337]

J. Brand, H. Braunschweig, S. S. Sen
B=B and B≡E (E = N and O) Multiple Bonds in the Coordination Sphere of Late Transition Metals
Acc. Chem. Res. 2014, 47, 180–191. [pdf]

 

Highlighted in:

"Bor-Chemie im Aufwind", M. Groß, Chem. unserer Zeit 2013, 47, 340. [pdf]



Dalton Trans.

[336]

C. Nagel, S. McLean, R. K Poole, H. Braunschweig, T. Kramer, U. Schatzschneider
Introducing [Mn(CO)3(tpa-κ3N)]+ as a novel photoactivatable CO-releasing molecule with well-defined iCORM intermediates - synthesis, spectroscopy, and antibacterial activity
Dalton Trans. 2014, 43, 9986–9997. [pdf]



Organometallics

[335]

H. Braunschweig, R. D. Dewhurst
Boron-Boron Multiple Bonding: From Charged to Neutral and Back Again
Organometallics 2014, 33, 6271–6277. [pdf]

 

[334]

H. Braunschweig, R. D. Dewhurst, T. Kramer, E. Siedler
A Simple Decarbonylative Route to Heterodinuclear Alkylborylene Complexes
Organometallics 2014, 33, 3877–3881. [pdf]

 

[333]

S. Bertsch, H. Braunschweig, R. D. Dewhurst, K. Radacki, C. Saalfrank, B. Wennemann, Q. Ye
Partially and Fully Reversible Solvation-Controlled Borylene Swapping and Metal-Only Lewis Pair Formation
Organometallics 2014, 33, 3649–3651. [pdf]

 

[332]

T. Arnold, H. Braunschweig, A. Damme, C. Hörl, T. Kramer, I. Krummenacher, J. Mager
Tin-Bridged ansa-Metallocenes of the Late Transition Metals Cobalt and Nickel: Preparation, Molecular and Electronic Structures, and Redox Chemistry
Organometallics 2014, 33, 1659–1664. [pdf]

 

[331]

H. Braunschweig, T. Dellermann, R. D. Dewhurst, J. Mies, K. Radacki, S. Stellwag-Konertz, A. Vargas
Strained ansa Half-Sandwich Complexes of Ruthenium and Osmium and a Non-Iron Metallopolymer by Ring-Opening Polymerization
Organometallics 2014, 33, 1536–1539. [pdf]

 

[330]

H. Braunschweig, A. Damme, R. D. Dewhurst, T. Kramer, I. Krummenacher, A. K. Phukan
Short Survey of the Chemical Reduction Behaviour of the Base-Stabilized Iron Dichloroboryl Complexes [(η5-C5Me5)Fe(CO)2BCl2(LB)]
Organometallics 2014, 33, 604–606. [pdf]

 

[329]

T. Arnold, H. Braunschweig, A. Damme, I. Krummenacher, K. Radacki
Synthesis and Structure of Group IV Distanna[2]metallocenophanes
Organometallics 2014, 33, 254–259. [pdf]



Acta Cryst.

[328]

H. Braunschweig, T. Kramer
Crystal structure of μ-1κC:2(η2)-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ2B:B-[1(η5)-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate
Acta Cryst. 2014, E70, 421-423. [pdf]