Publications 2022


Angew. Chem.

[648]

W. Lu, A. Jayaraman, F. Fantuzzi, R. D. Dewhurst, M. Härterich, M. Dietz, S. Hagspiel, I. Krummenacher, K. Hammond, J. Cui, H. Braunschweig

An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry
Angew. Chem. 2022134, e202113947; [pdf] Angew. Chem. Int. Ed. 202261, e202113947. [pdf]



J. Am. Chem. Soc.

[647]

A. Stoy, M. Härterich, R. D. Dewhurst, J. O. Jimenez-Halla, P. Endres, M. Eißelein, T. Kupfer, A. Deissenberger, T. Thiess, H. Braunschweig

Evidence for Borylene Carbonyl (LHB=C=O) and Base-Stabilized (LHB=O) and Base-Free Oxoborane (RB≡O) Intermediates in the Reactions of Diborenes with CO2
J. Am. Chem. Soc. 2022144, 3376-3380. [pdf]



Chem. Sci.

[646]

D. Dhara, A. Jayaraman, M. Härterich, R. D. Dewhurst, H. Braunschweig

Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules
Chem. Sci. 202213, 5631-5638. [pdf]

 

[645]

F. Fantuzzi, Y. Jiao, R. D. Dewhurst, F. Weinhold, H. Braunschweig, B. Engels

Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes?
Chem. Sci. 202213, 5118-5129. [pdf]

 

[644]

S. Fuchs, A, Jayaraman, I. Krummenacher, L. Haley, M. Baštovanović, M. Fest, K. Radacki, H. Helten, H. Braunschweig

Diboramacrocycles: reversible borole dimerisation-dissociation systems
Chem. Sci. 202213, 2932-2938. [pdf]



J. Org. Chem.

[643]

A. K. Swain, K. Radacki, H. Braunschweig, P. Ravat

Pyrene-Fused [7]Helicenes Connected via Hexagonal and Heptagonal Rings: Stereospecific Synthesis and Chiroptical Properties
J. Org. Chem. 202287, 993-1000. [pdf]



Chem. Eur. J.

[642]

A. Maiti, B. J. Elvers, S. Bera, F. Lindl, I. Krummenacher, P. Ghosh, H. Braunschweig, C. B. Yildiz, C. Schulzke, A. Jana

Disclosing Cyclic(Alkyl)(Amino)Carbenes as a One-Electron Reductant: Synthesis of Acyclic(Amino)(Aryl)Carbene-Based Kekulé Diradicaloids
Chem. Eur. J. 202228, e202104567. [pdf]

 

[641]

F. Fantuzzi, R. Moral, R. D. Dewhurst, H. Braunschweig, A. K. Phukan

Probing the Potential of Hitherto Unexplored Base-Stabilized Borylenes in Dinitrogen Binding
Chem. Eur. J. 202228, e202104123. [pdf]

 

[640]

M. Huang, J. Hu, I. Krummenacher, A. Friedrich, H. Braunschweig, S. A. Westcott, U. Radius, T. B. Marder

Base-Mediated Radical Borylation of Alkyl Sulfones
Chem. Eur. J. 202228, e202103866. [pdf]



Chem. Commun.

[639]

F. Lindl, F. Fantuzzi, L. Mailänder, C. Hörl, G. Bélanger-Chabot, H. Braunschweig

Azidoborolate anions and azidoborole adducts: isolable forms of an unstable borole azide
Chem. Commun. 202258, 4735-4738. [pdf]

 

[638]

S. Kachel, A. Jayaraman, A. Okorn, I. Krummenacher, R. Drescher, C. Brunecker, S. Fuchs, M. Heß, T. E. Stennett, H. Braunschweig

Azide-alkyne cycloadditions with an electronically activated alkyne: indole formation via 1-aryl-1,2,3-triazole-derived imino carbenes
Chem. Commun. 202258, 2331-2334. [pdf]



Dalton Trans.

[637]

F. Schorr, M. Arrowsmith, F. Fantuzzi, A. Rempel, H. Braunschweig

1,2-Dialkynyldiboranes(4): B–B versus C≡C bond reactivity
Dalton Trans. 202251, 6197–6203. [pdf]



Macromolecules

[636]

J. Selby, M. Holzapfel, K. Radacki, A. K. Swaina, H. Braunschweig, C. Lambert

Polymeric Indolenine-Squaraine Foldamers with a Preferred Helix Twist Sense and their Chiroptical Absorption and Emission Properties
Macromolecules 202255, 421–436. [pdf]