Publications 2022

Angew. Chem.


W. Lu, A. Jayaraman, F. Fantuzzi, R. D. Dewhurst, M. Härterich, M. Dietz, S. Hagspiel, I. Krummenacher, K. Hammond, J. Cui, H. Braunschweig

An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry
Angew. Chem. 2022134, e202113947; [pdf] Angew. Chem. Int. Ed. 202261, e202113947. [pdf]

J. Am. Chem. Soc.


A. Stoy, M. Härterich, R. D. Dewhurst, J. O. Jimenez-Halla, P. Endres, M. Eißelein, T. Kupfer, A. Deissenberger, T. Thiess, H. Braunschweig

Evidence for Borylene Carbonyl (LHB=C=O) and Base-Stabilized (LHB=O) and Base-Free Oxoborane (RB≡O) Intermediates in the Reactions of Diborenes with CO2
J. Am. Chem. Soc. 2022144, 3376-3380. [pdf]

Chem. Sci.


D. Dhara, A. Jayaraman, M. Härterich, R. D. Dewhurst, H. Braunschweig

Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules
Chem. Sci. 202213, 5631-5638. [pdf]



F. Fantuzzi, Y. Jiao, R. D. Dewhurst, F. Weinhold, H. Braunschweig, B. Engels

Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes?
Chem. Sci. 202213, 5118-5129. [pdf]



S. Fuchs, A, Jayaraman, I. Krummenacher, L. Haley, M. Baštovanović, M. Fest, K. Radacki, H. Helten, H. Braunschweig

Diboramacrocycles: reversible borole dimerisation-dissociation systems
Chem. Sci. 202213, 2932-2938. [pdf]

J. Org. Chem.


A. K. Swain, K. Radacki, H. Braunschweig, P. Ravat

Pyrene-Fused [7]Helicenes Connected via Hexagonal and Heptagonal Rings: Stereospecific Synthesis and Chiroptical Properties
J. Org. Chem. 202287, 993-1000. [pdf]

Chem. Eur. J.


A. Maiti, B. J. Elvers, S. Bera, F. Lindl, I. Krummenacher, P. Ghosh, H. Braunschweig, C. B. Yildiz, C. Schulzke, A. Jana

Disclosing Cyclic(Alkyl)(Amino)Carbenes as a One-Electron Reductant: Synthesis of Acyclic(Amino)(Aryl)Carbene-Based Kekulé Diradicaloids
Chem. Eur. J. 202228, e202104567. [pdf]



F. Fantuzzi, R. Moral, R. D. Dewhurst, H. Braunschweig, A. K. Phukan

Probing the Potential of Hitherto Unexplored Base-Stabilized Borylenes in Dinitrogen Binding
Chem. Eur. J. 202228, e202104123. [pdf]



M. Huang, J. Hu, I. Krummenacher, A. Friedrich, H. Braunschweig, S. A. Westcott, U. Radius, T. B. Marder

Base-Mediated Radical Borylation of Alkyl Sulfones
Chem. Eur. J. 202228, e202103866. [pdf]

Chem. Commun.


F. Lindl, F. Fantuzzi, L. Mailänder, C. Hörl, G. Bélanger-Chabot, H. Braunschweig

Azidoborolate anions and azidoborole adducts: isolable forms of an unstable borole azide
Chem. Commun. 202258, 4735-4738. [pdf]



S. Kachel, A. Jayaraman, A. Okorn, I. Krummenacher, R. Drescher, C. Brunecker, S. Fuchs, M. Heß, T. E. Stennett, H. Braunschweig

Azide-alkyne cycloadditions with an electronically activated alkyne: indole formation via 1-aryl-1,2,3-triazole-derived imino carbenes
Chem. Commun. 202258, 2331-2334. [pdf]

Dalton Trans.


F. Schorr, M. Arrowsmith, F. Fantuzzi, A. Rempel, H. Braunschweig

1,2-Dialkynyldiboranes(4): B–B versus C≡C bond reactivity
Dalton Trans. 202251, 6197–6203. [pdf]



J. Selby, M. Holzapfel, K. Radacki, A. K. Swaina, H. Braunschweig, C. Lambert

Polymeric Indolenine-Squaraine Foldamers with a Preferred Helix Twist Sense and their Chiroptical Absorption and Emission Properties
Macromolecules 202255, 421–436. [pdf]