[703]

M. Härterich, A. Matler, R. D. Dewhurst, A. Sachs, K. Oppel, A. Stoy, H. Braunschweig

A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl
Nature Communications 2023, 14, Article number: 2764. [link]

[702]

P. Saha, N. Chrysochos, B. J. Elvers, S. Pätsch, S. I. Uddin, I. Krummenacher, M. Nandeshwar, G. P. Sankar, H. Braunschweig, P. Ravat, C. Schulzke, A. Jana

Bis-Olefin Based Crystalline Schlenk Hydrocarbon Diradicals with a Triplet Ground State

Angew. Chem. 2023, 135, e202311868; [pdf]  Angew. Chem. Int. Ed. 2023, 62, e202311868. [pdf]

[701]

S. Nees, T. Wellnitz, F. Dankert, S. Dotzauer, M. Härterich, M. Feldt, H. Braunschweig, C. Hering-Junghans

On the Reactivity of Phosphaalumenes towards C−C Multiple Bonds
Angew. Chem. 2023, 135, e202215838; [pdf] Angew. Chem. Int. Ed. 2023, 62, e202215838. [pdf]

[700]

T. Brückner, B. Ritschel, J. O. C. Jiménez-Halla, F. Fantuzzi, D. Duwe, R. D. Dewhurst, H. Braunschweig

Metal-Free Intermolecular C–H Borylation of N-Heterocycles at B–B Multiple Bonds
Angew. Chem. 2023, 135, e202213284; [pdf] Angew. Chem. Int. Ed. 2023, 62, e202213284. [pdf]

[699]

L. C. Haufe, L. Endres, M. Arrowsmith, R. Bertermann, M. Dietz, F. Fantuzzi, M. Finze, H. Braunschweig

Boron Insertion into the N≡N bond of a Tungsten Dinitrogen Complex
J. Am. Chem. Soc. 2023, 145, 23986–23993. [pdf]

[698]

M. Heinz, M. Arrowsmith, J. I. Schweizer, I. Krummenacher, M. C. Holthausen, H. Braunschweig

Experimental and Computational Study of a Confirmed Borylene-to-Diborene Dimerization
J. Am. Chem. Soc. 2023, 145, 22685–22696. [pdf]

[697]

M. Dietz, M. Arrowsmith, L. Endres, V. Paprocki, B. Engels, H. Braunschweig

Synthesis and Reactivity of Highly Electron-Rich Zerovalent Group 10 Diborabenzene Pogo-Stick and Half-Sandwich Complexes
J. Am. Chem. Soc. 2023, 145, 22222–22231. [pdf]

[696]

M. Dietz, M. Arrowsmith, K. Drepper, A. Gärtner, I. Krummenacher, R. Bertermann, M. Finze, H. Braunschweig

Structure and Electronics of a Series of CAAC-Stabilized Diboron-Doped Acenes from 1,4-Diboranaphthalene to 6,13-Diborapentacene
J. Am. Chem. Soc. 2023, 145, 15001–15015. [pdf]

[695]

A. Gärtner, U. S. Karaca, M. Rang, M. Heinz, P. D. Engel, I. Krummenacher, M. Arrowsmith, A. Hermann, A. Matler, A. Rempel, R. Witte, H. Braunschweig, M. C. Holthausen, M.-A. Légaré

Achieving Control over the Reduction/Coupling Dichotomy of N₂ by Boron Metallomimetics
J. Am. Chem. Soc. 2023, 145, 8231–8241. [pdf]

[694]

J. L. Bohlen, L. Endres, R. Drescher, K. Radacki, M. Dietz, I. Krummenacher, H. Braunschweig

Boroles from alumoles: accessing boroles with alkyl-substituted backbones via transtrielation
Chem. Sci. 2023, 14, 9010-9015. [pdf]

[693]

Y. K. J. Bejaoui, F. Philippi, H.-G. Stammler, K. Radacki, L. Zapf, N. Schopper, K. Goloviznina, K. A. M. Maibom, R. Graf, J. A. P. Sprenger, R. Bertermann, H. Braunschweig, T. Welton, N. V. Ignat´ev, M. Finze

Insights to structure-property relationships in ionic liquids using cyclic perfluoroalkylsulfonylimides
Chem. Sci. 2023, 14, 2200-2214. [pdf]

[692]

S. Jana, B. J. Elvers, S. Pätsch, P. Sarkar, I. Krummenacher, M. K. Nayak, A. Maiti, N. Chrysochos, S. K. Pati, C. Schulzke, H. Braunschweig, C. B. Yildiz, A. Jana

Air and Moisture Stable para- and ortho-Quinodimethane Derivatives Derived from bis-N-Heterocyclic Olefins
Org. Lett. 2023, 25, 1799–1804. [pdf] 

[691]

Z. Wu, N. Hippchen, J. Han, L. Ji, A. Friedrich, I. Krummenacher, H. Braunschweig, J. Krebs, M. Moos, P. Biegger, O. Tverskoy, S. Maier, C. Lambert, A. Dreuw, T. B. Marder, J. Freudenberg, U. H. F. Bunz

The Radical Anion and Dianion of Benzo[3,4]cyclobuta[1,2-b]phenazine
J. Org. Chem. 2023, 88, 2742–2749. [pdf]

[690]

A. Maiti, B. J. Elvers, S. Bera, F. Lindl, I. Krummenacher, P. Ghosh, H. Braunschweig, C. B. Yildiz, C. Schulzke, H.-G. Korth, A. Jana

Comment on “Disclosing Cyclic(Alkyl)(Amino)Carbenes as a One-Electron Reductant: Synthesis of Acyclic(Amino)(Aryl)Carbene-Based Kekulé Diradicaloids”

Chem. Eur. J. 2023, 29, e202302848. [pdf]

[689]

W. Lu, N. Hensiek, K. Saha, R. D. Dewhurst, M. Härterich, C. Pranckevicius, S. Hagspiel, M. Dietz, I. Krummenacher H. Braunschweig

Electron-Precise Dicationic Tetraboranes: Syntheses, Structures and Rearrangement to an Alkylidene Borate-Borenium Zwitterion and a 1,3-Azaborinine
Chem. Eur. J. 2023, 29, e202300644. [pdf]

[688]

C. Czernetzki, T. Tröster, L. Endres, F. Endres, M. Arrowsmith, A. Gärtner, F. Fantuzzi, H. Braunschweig

Synthesis, Structural Characterization, and Bonding of Molecular Heavier Beryllium Chalcogenides
Chem. Eur. J. 2023, 29, e202301418. [pdf]

[687]

F. Schorr, T. Keim, M. Arrowsmith, A. Vargas, R. D. Dewhurst, I. Krummenacher, H. Braunschweig

Thienyl-Substituted Diboranes(4): Electronic Stabilization of Radicals Versus Increased Reactivity towards Bond Activation
Chem. Eur. J. 2023, 29, e202301286. [pdf]

[686]

L. Xiang, J. Wang, I. Krummenacher, K. Radacki, H. Braunschweig, Z. Lin, Q. Ye

Persistent and Predominantly Localized Boron Radical from the Reduction of a Three-dimensional Analogue of NHC-Stabilized Borafluorenium
Chem. Eur. J. 2023, 29, e202301270. [pdf]

[685]

D. Dhara, A. Jayaraman, M. Härterich, M. Arrowsmith, M. Jürgensen, M. Michel, H. Braunschweig

Trapping of a Transient Base-Stabilised Alumylene and Alumylene-Type Reactivity of a Self-Stabilising Dialumene towards Organic Azides
Chem. Eur. J. 2023, 29, e202300483. [pdf]

[684]

T. Bischof, L. Beßler, I. Krummenacher, L. Erhard, H. Braunschweig, M. Finze

Construction of a Diverse Range of Boron Heterocycles via Ring Expansion of a Carboranyl-Substituted 9-Borafluorene
Chem. Eur. J. 2023, 29, e202300210. [pdf]

[683]

R. Witte, M. Arrowsmith, A. Lamprecht, I. Krummenacher, H. Braunschweig

C‒C and C‒N Bond Activation, Lewis-Base Coordination and One- and Two-Electron Oxidation at a Linear Aminoborylene
Chem. Eur. J. 2023, 29, e202203663. [pdf]

[682]

F. Lindl, A. Lamprecht, M. Arrowsmith, E. Khitro, A. Rempel, M. Dietz, T. Wellnitz, G. Bélanger-Chabot, A. Stoy, V. Paprocki, D. Prieschl, C. Lenczyk, J. Ramler, C. Lichtenberg H. Braunschweig

Aromatic 1,2-Azaborinin-1-yls as Electron-Withdrawing Anionic Nitrogen Ligands for Main Group Elements
Chem. Eur. J. 2023, 29, e202203345. [pdf]

[681]

R. Dolai, B. J. Elvers, T. Singh, N. Chrysochos, R. Kumar, B. Joseph, M. K. Nayak, A. Maiti, A. Jayaraman, I. Krummenacher, J. Mondal, H. Braunschweig, C. B. Yildiz, C. Schulzke, A. Jana

Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC vs. CAAC as Donor Substituents
Chem. Eur. J. 2023, 29, e202202888. [pdf]

[680]

V. Zeh, J. S. Schneider, J. Bachmann, I. Krummenacher, H. Braunschweig, H. Helten

Poly(ferrocenyleneiminoborane): an inorganic–organic hybrid polymer comprising a backbone of moderately interacting ferrocenes
Chem. Commun. 2023, 59, 13723-13726. [pdf]

[679]

N. Chrysochos, S. Pätsch, B. J. Elvers, I. Krummenacher, N. M. Giridhar, G. Prabusankar, H. Braunschweig, C. Schulzke, P. Ravat, A. Jana

Introducing an orthogonally polarized electron-rich alkene synthesis of a zwitterionic boron-Containing π-conjugated system
Chem. Commun. 2023, 59, 12350-12353. [pdf]

[678]

A. Lamprecht, F. Lindl, L. Endres, I. Krummenacher, H. Braunschweig

Coinage metal complexes of BN analogues of m-terphenyl ligands
Chem. Commun. 2023, 59, 10149-10152. [pdf]

[677]

T. Tröster, F. Endres, M. Arrowsmith, L. Endres, F. Fantuzzi, H. Braunschweig

Dibenzoberylloles: antiaromatic s-block fluorene analogues
Chem. Commun. 2023, 59, 9199-9202. [pdf]

[676]

J. S. Schneider, I. Krummenacher, H. Braunschweig, H. Helten

Linear and macrocyclic oligo(p-phenylene iminoboranes) with ferrocenyl side groups – observation of selective, non-templated macrocyclization
Chem. Commun. 2023, 59, 8408-8411. [pdf]

[675]

D. Čavlović, O. Blacque, I. Krummenacher, H. Braunschweig, P. Ravat, M. Juríček

Dimethylnonacethrene – en route to a magnetic switch
Chem. Commun. 2023, 59, 7743-7746. [pdf]

[674]

T. Bischof, N. Wieprecht, S. Fuchs, L. Endres, I. Krummenacher, M. Michel, C. Mihm, H. Braunschweig, M. Finze

Unlocking Heteroaromatic Ring Systems through Chalcogen Insertion into Boroles
Inorg. Chem. 2023, 62, 21329–21335. [pdf]

[673]

B. Chakraborty, F. E. Basumatary, H. Braunschweig, A. K. Phukan

Cooperative Activation of Small Molecules by Base-Stabilized Borylenes
Inorg. Chem. 2023, 62, 9063–9076. [pdf]

[672]

D. Čavlović, O. Blacque, I. Krummenacher, H. Braunschweig, P. Ravat, M. Juríček

Dimethylnonacethrene – En Route to a Magnetic Switch
ChemRxiv 2023, doi: 10.26434/chemrxiv-2023-3fbgs. [link]

[671]

S. Huynh, M. Arrowsmith, L. Meier, M. Dietz, M. Härterich, M. Michel, A. Gärtner, H. Braunschweig

Cyclic alkyl(amino)iminates (CAAIs) as strong 2σ,4π-electron donor ligands for the stabilisation of boranes and diboranes(4): a synthetic and computational study
Dalton Trans. 2023, 52, 3869-3876. [pdf]

[670]

J. Weiser, J. Cui, R. D. Dewhurst, H. Braunschweig, B. Engels, F. Fantuzzi

Structure and bonding of proximity-enforced main-group dimers stabilized by a rigid naphthyridine diimine ligand
J. Comput. Chem. 2023, 44, 456-467. [pdf]

[669]

S. Nees, H. Beer, P. Just, L. M. Teichmeier, L. E. Christoffer, A. Guljam, Kushik, H. Braunschweig, C. Hering-Junghans

On the reactivity of Mes*P(PMe₃) towards Al(I) compounds - Evidence for the Intermediate Formation of Phosphaalumenes
ChemPlusChem 2023, 88, e202300078. [pdf]

[668]

D. E. Trujillo-González, G. G. García, T. A. Hamlin, F. M. Bickelhaupt, H. Braunschweig, J. O. C. Jiménez-Halla, M. Solà

The Search for Enhanced σ-Donor Ligands to Stabilize Boron-Boron Multiple Bonds
Eur. J. Inorg. Chem. 2023, 26, e202200767. [pdf]