Publications 2025
Chem
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[779] |
E. Beck, I. Krummenacher, T. Kupfer, M. Dietz, M. Michel, K. Hammond, H. Braunschweig Structural stability of a bent tetra(amino)tetraborane ring across four charge states Chem 2025, 11, 102338. [pdf]
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Nat. Commun.
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[778] |
E. Beck, D. Bröllos, I. Krummenacher, T. Kupfer, M. Dietz, T. Wellnitz, C. Mihm, H. Braunschweig Boron-chalcogen heterocycles and linear tetraboranes from a cyclic tetra(amino)tetraborane Nat. Commun. 2025, 16, Article number: 5304. [link]
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[777] |
M. Buckel, J. Klopf, J. S. Schneider, A. Lik, N. A. Riensch, I. Krummenacher, H. Braunschweig, B. Engels, H. Helten A fully conjugated meso-boron-substituted porphyrinoid combining Lewis acidity with redox-switchable aromaticity Nat. Commun. 2025, 16, Article number: 1775. [link] |
Sci. Adv.
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[776] |
E. Beck, I. Krummenacher, T. Kupfer, M. Dietz, H. Braunschweig Capturing carbon monoxide – Accessing bis(boryl)ketones through direct B−B bond carbonylation Sci. Adv. 2025, 11, eadz3520. [pdf] |
J. Am. Chem. Soc.
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[775] |
S. Kar, K. Saha, V. Binilkrishna, I. Krummenacher, R. D. Dewhurst, H. Braunschweig Direct Interconversion between Bis(borylenes) and Diborenes J. Am. Chem. Soc. 2025, 147, 44562–44571. [pdf]
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[774] |
J. Han, H. Xu, A. Sharma, J. Asatryan, F. Rauch, A. Friedrich, J. Krebs, L. Swoboda, J. Schuster, S. Pagidi, N. K. Kalluvettukuzhy, M. Alqurashi, P. Thilagar, N. Schopper, I. Krummenacher, V. Stepanenko, M. Finze, H. Braunschweig, J. Martín, F. Würthner, D. Baran, T. B. Marder Understanding Twisted Triarylboranes from Single Crystals to Heterojunction Blends and Their Applications in Organic Photovoltaics J. Am. Chem. Soc. 2025, 147, 28694–28713. [pdf]
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[773] |
M. Müller, J. Klopf, A. Friedrich, S. Lutz, M. Buckel, I. Krummenacher, H. Braunschweig, B. Engels, H. Helten
BNB-Modified Perylene, Terrylene, and Quaterrylene Diimides: Introduction of the π-Accepting and Aggregation-Suppressing Diborinic Imide Group in Rylene Dyes J. Am. Chem. Soc. 2025, 147, 28289–28302. [pdf]
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[772] |
M. Neder, M. Arrowsmith, L. Endres, C. Mihm, S. Nees, R. Bertermann, H. Braunschweig Highly Antiaromatic Naphtho-1,2-Diboretes as Precursors for Tunable, Unsymmetrical 1,4-Diboraanthracenes J. Am. Chem. Soc. 2025, 147, 23034–23048. [pdf] |
Angew. Chem.
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[771] |
F. Saal, V. Brancaccio, K. Radacki, H. Braunschweig, P. Ravat Spring-Like Behavior in [8]Helicene Diimides: How Helical Pitch Governs Optical Anisotropy and Electronic Conjugation Angew. Chem. 2025, 137, e202508779; Angew. Chem. Int. Ed. 2025, 64, e202508779. [pdf]
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[770] |
T. Wellnitz, E. Zander, L. Wüst, J. Boardman, M. Neubauer, S. Nees, H. Braunschweig, C. Hering-Junghans Reactivity of Pnictaalumenes Towards 1,3-Dipole Molecules Angew. Chem. 2025, 137, e202506356; Angew. Chem. Int. Ed. 2025, 64, e202506356. [pdf]
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[769] |
M. Riethmann, L. Eyßelein, I. Krummenacher, R. Bertermann, H. Braunschweig, M. Gerken, M. Finze, U. Radius A Joyful Journey: Tungsten(VI) and Tungsten(V) Fluorides Meet N-Heterocyclic Carbenes and Cyclic (Alkyl)(Amino)carbenes Angew. Chem. 2025, 137, e202504498; Angew. Chem. Int. Ed. 2025, 64, e202504498. [pdf]
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[768] |
Y. Konrad, A. Jayaraman, I. Krummenacher, H. Braunschweig Formation and Metallomimetic Reactivity of a Transient Dicoordinate Alkylborylene Angew. Chem. 2025, 137, e202423669; [pdf] Angew. Chem. Int. Ed. 2025, 64, e202423669. [pdf]
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[767] |
P. H. R. Oliveira, M. O. Rodrigues, C. D. G. da Silva, J. Bohlen, M. Arrowsmith, A. Jayaraman, L. Lubczyk, F. Fantuzzi, E. N. da Silva Júnior, H. Braunschweig Straightforward Formation of Borirenes from Boroles and Dialkynes Angew. Chem. 2025, 137, e202423391; [pdf] Angew. Chem. Int. Ed. 2025, 64, e202423391. [pdf]
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Nat. Synth.
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[766] |
M. Michel, S. Kar, L. Endres, R. D. Dewhurst, B. Engels, H. Braunschweig The synthesis of a neutral boryne Nat. Synth. 2025, 4, 869–876. [link]
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Chem. Sci.
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[765] |
C. Markl, S. Kar, L. Lubczyk, K. Hammond, R. D. Dewhurst, H. Braunschweig
Simple, one-step syntheses of tri- and tetracyclic B,N,S-heterocycles from reactions of a diboracumulene with thiols Chem. Sci. 2025, 16, 18911–18918. [pdf]
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[764] |
L. Wüst, J. Chorbacher, T. Keim, T. Wellnitz, J. Spieß, N. Wieprecht, M. Michel, H. Helten, H. Braunschweig Tuning the emission properties of luminescent 1,2,3-diazaborinates Chem. Sci. 2025, 16, 15086–15096. [pdf]
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[763] |
C. Mihm, S. Kar, A. Sachs, D. Duwe, R. D. Dewhurst, H. Braunschweig Synthesis of symmetrical and unsymmetrical cyclic diborenes via NHC-directed C–H borylation Chem. Sci. 2025, 16, 11637–11643. [pdf]
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[762] |
L. Wüst, L. Scheuring, T. Wellnitz, K. Radacki, H. Braunschweig Alkali metal salts of 1,2,3-benzodiazaborines: platforms for late-stage N-functionalization and metal complexation Chem. Sci. 2025, 16, 9934–9942. [pdf]
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[761] |
M. Agati, S. Romi, S. Fanetti, K. Radacki, M. Hanfland, H. Braunschweig, T. B. Marder, S. J. Clark, A. Friedrich, R. Bini Insights into topochemical versus stress-induced high-pressure reactivity of azobenzene by single crystal X-ray diffraction Chem. Sci. 2025, 16, 9240–9254. [pdf]
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[760] |
M. Jürgensen, T. Kunz, M. Arrowsmith, M. Dietz, S. Hagspiel, H. Braunschweig Synthesis and reactivity of a parent phosphathioethynolato-borane and a boraarsaketene Chem. Sci. 2025, 16, 8870–8877. [pdf]
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[759] |
L. Wüst, J. Chorbacher, T. Wellnitz, S. Nees, H. Helten, H. Braunschweig Synthetic access to organyl-substituted 1,2,3-benzodiazaborines with turn-on fluorescence activity Chem. Sci. 2025, 16, 7284–7293. [pdf]
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[758] |
M. Michel, L. Endres, F. Fantuzzi, I. Krummenacher, H. Braunschweig Harnessing transient CAAC-stabilized mesitylborylenes for chalcogen activation Chem. Sci. 2025, 16, 5632–5639. [pdf]
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[757] |
M. S. Luff, T. M. Filipovic, C. S. Corsei, K. Oppel, I. Krummenacher, R. Bertermann, M. Finze, H. Braunschweig, U. Radius Azolium-2-dithiocarboxylates as redox active ligands in nickel chemistry Chem. Sci. 2025, 16, 5142–5154. [pdf] |
Biomater. Sci.
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[756] |
A. V. Hauck, P. Komforth, J. Erlenbusch, J. Stickdorn, K. Radacki, H. Braunschweig, P. Besenius, S. Van Herck, L. Nuhn Aliphatic polycarbonates with acid degradable ketal side groups as multi-pH-responsive immunodrug nanocarriers Biomater. Sci. 2025, 13, 1414–1425. [pdf] |
Chem. Commun.
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[755] |
N. Hensiek, D. Duwe, M. Arrowsmith, M. Michel, H. Braunschweig
Atom-efficient synthesis of BN-heterocycles from oligoboranes and isonitriles Chem. Commun. 2025, 61, 14721–14724. [pdf]
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[754] |
T. Wellnitz, L. Wüst, H. Braunschweig, C. Hering-Junghans A BNAlP-heterocycle Chem. Commun. 2025, 61, 4014–4017. [pdf] |
Inorg. Chem. Front.
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[753] |
A. Häfner, L. Endres, M. Arrowsmith, C. Mimh, S. Fuchs, S. Nees, K. Radacki, I. Krummenacher, R. Bertermann, F. Fantuzzi, H. Braunschweig Synthesis and reactivity of a benzo-fused 1,2-diborete biradicaloid Inorg. Chem. Front. 2025, 12, 5493–5505. [link] |
Inorg. Chem.
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[752] |
L. Xiang, J. Wang, A. Matler, I. Krummenacher, H. Braunschweig, Q. Ye
A Lewis Superacidic Borirane Derivative Featuring a Tris(Carboranyl)Borane Environment Inorg. Chem. 2025, 64, 25428–25435. [pdf]
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[751] |
M. Passargus, M. Arrowsmith, R. Bertermann, M. Finze, H. Braunschweig
Reactivity of a Diplatinum-Templated BNBN Analogue of Butatriene Toward Azides Inorg. Chem. 2025, 64, 21111–21129. [pdf]
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[750] |
M. Dietz, M. Arrowsmith, A. Jayaraman, A. Lamprecht, H. Braunschweig Reactivity of a Stable and Highly Electron-Rich (η6-Diborabenzene)nickel(0) Synthon Inorg. Chem. 2025, 64, 1788–1797. [pdf] |
Chem. Eur. J.
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[749] |
P. Saha, N. Chrysochos, B. J. Elvers, S. S. M. Bandaru, T. Gangber, K. Gaur, I. Krummenacher, H. Braunschweig, V. Chandrasekhar, P. Ravat, C. Schulzke, A. Jana
Thienylene-Based Diradicaloids: Electrochromic Ring-Closing of Dithienylethene-Based Bis-Amidinium Cation Chem. Eur. J. 2025, 31, e02914. [pdf]
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[748] |
K. A. M. Maibom, C. Breitenstein, S. Lorenzen, T. Knuplez, L. N. Schneider, Y. B. J. Bejaoui, J. Gierling, K. Radacki, H. Braunschweig, C. Deutsch, M. Shan, T. Fuchß, M. Schulte, N. V. Ignat’ev, M. Finze N,N-Bis(trifluoromethyl)aminoacetonitrile: A Versatile Building Block for the Introduction of the Bis(trifluoromethyl)amino Group Chem. Eur. J. 2025, 31, e202501550. [pdf]
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[747] |
J. S. Schneider, V. Zeh, J. Klopf, P. M. Schneider, J. Bachmann, I. Krummenacher, H. Braunschweig, H. Helten Poly(Ferrocenylene Iminoborane) and the Merging of 1,1’-Ferrocenylene with p-Phenylene Iminoborane Building Blocks into Alternating Copolymers, Oligomers, and Macrocycles Chem. Eur. J. 2025, 31, e202404533. [pdf]
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[746] |
Y. Zhang, A. Matler, J. Krebs, I. Krummenacher, Q. Ye, H. Braunschweig, T. B. Marder, L. Ji Emission-Tunable B←N Lewis Pair-Functionalized Naphthalenes: Synthesis, Structures, and Properties Chem. Eur. J. 2025, 31, e202403973. [pdf] |
ChemRxiv
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[745] |
A. A. C. Hartmann, V. Brancaccio, K. Radacki, H. Braunschweig, P. Ravat High-Dissymmetry Chiroptical Switching in Proton–Responsive [8]Helicene Bisbenzimidazoles ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-q2krc. [link]
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[744] |
D. Dhara, L. Endres, C. Souza, R. Dewhurst, M. Zlatar, F. Fantuzzi, H. Braunschweig A Neutral All-Aluminium Aromatic ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-hxz3v. [link]
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[743] |
Y. Konrad, M. Arrowsmith, H. Braunschweig Isolation and Cycloaddition Reactions of a Stable Boraketene ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-l9qnb. [link]
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[742] |
F. Saal, V. Brancaccio, K. Radacki, H. Braunschweig, P. Ravat Spring-Like Behavior in [8]Helicene Diimides: How Helical Pitch Governs Optical Anisotropy and Electronic Conjugation ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-m6825. [link] |
arXiv
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[741] |
L. Schraut-May, S. Hammer, L. N. Philipp, K. Radacki, G. Tauscher, H. Holstein, K. Strauß, M. Kamp, H. Schwörer, H. Braunschweig, R. Mitric, J. Pflaum Competing excitonic couplings as origin of mimicked phase transitions in zinc-phthalocyanine single crystals arXiv (cond-mat.mtrl-sci) 2025, doi: 10.48550/arXiv.2512.02639. [link] |
Dalton Trans.
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[740] |
S. Dotzauer, S. Kar, T. Swoboda, C. Weidemann, A. Häfner, R. D. Dewhurst, H. Braunschweig Synthesis of base-free boriranes and their conversion to borirenes using strong reductant Dalton Trans. 2025, 54, 3857–3862. [pdf]
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[739] |
B. Chakraborty, R. R. Hazarika, H. Braunschweig, A. K. Phukan Binding of base-stabilized borylenes with transition metals and formation of metal only Lewis pairs Dalton Trans. 2025, 54, 842–850. [pdf] |
J. Phys. Chem. B
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[738] |
L. Euringer, M. Holzapfel, I. Krummenacher, H. Braunschweig, C. Lambert Switching from Transition-State Theory to Solvent-Controlled Adiabatic Charge-Transfer Regime in Bis-Triarylamine Mixed Valence Radical Cations by Modification of the Bridge Electron Density J. Phys. Chem. B 2025, 129, 4197–4206. [pdf] |