[753]

E. Beck, I. Krummenacher, T. Kupfer, M. Dietz, M. Michel, K. Hammond, H. Braunschweig

Structural stability of a bent tetra(amino)tetraborane ring across four charge states

Chem 2025, 11, 102338. [pdf]

[752]

M. Buckel, J. Klopf, J. S. Schneider, A. Lik, N. A. Riensch, I. Krummenacher, H. Braunschweig, B. Engels, H. Helten

A fully conjugated meso-boron-substituted porphyrinoid combining Lewis acidity with redox-switchable aromaticity

Nat. Commun. 2025, 16, Article number: 1775. [link]

[751]

Y. Konrad, A. Jayaraman, I. Krummenacher, H. Braunschweig

Formation and Metallomimetic Reactivity of a Transient Dicoordinate Alkylborylene

Angew. Chem. 2025, 137, e202423669; [pdf] Angew. Chem. Int. Ed. 2025, 64, e202423669. [pdf]

[750]

P. H. R. Oliveira, M. O. Rodrigues, C. D. G. da Silva, J. Bohlen, M. Arrowsmith, A. Jayaraman, L. Lubczyk, F. Fantuzzi, E. N. da Silva Júnior, H. Braunschweig

Straightforward Formation of Borirenes from Boroles and Dialkynes

Angew. Chem. 2025, 137, e202423391; [pdf] Angew. Chem. Int. Ed. 2025, 64, e202423391. [pdf]

[749]

L. Wüst, J. Chorbacher, T. Wellnitz, S. Nees, H. Helten, H. Braunschweig

Synthetic access to organyl-substituted 1,2,3-benzodiazaborines with turn-on fluorescence activity

Chem. Sci. 2025, 16, 7284-7293. [pdf]

[748]

M. Michel, L. Endres, F. Fantuzzi, I. Krummenacher, H. Braunschweig

Harnessing transient CAAC-stabilized mesitylborylenes for chalcogen activation

Chem. Sci. 2025, 16, 5632-5639. [pdf]

[747]

M. S. Luff, T. M. Filipovic, C. S. Corsei, K. Oppel, I. Krummenacher, R. Bertermann, M. Finze, H. Braunschweig, U. Radius

Azolium-2-dithiocarboxylates as redox active ligands in nickel chemistry

Chem. Sci. 2025, 16, 5142-5154. [pdf]

[746]

A. V. Hauck, P. Komforth, J. Erlenbusch, J. Stickdorn, K. Radacki, H. Braunschweig, P. Besenius, S. Van Herck, L. Nuhn

Aliphatic polycarbonates with acid degradable ketal side groups as multi-pH-responsive immunodrug nanocarriers

Biomater. Sci. 2025, 13, 1414-1425. [pdf]

[745]

T. Wellnitz, L. Wüst, H. Braunschweig, C. Hering-Junghans

A BNAlP-heterocycle

Chem. Commun. 2025, 61, 4014–4017. [pdf]

[744]

M. Dietz, M. Arrowsmith, A. Jayaraman, A. Lamprecht, H. Braunschweig

Reactivity of a Stable and Highly Electron-Rich (η⁶-Diborabenzene)nickel(0) Synthon

Inorg. Chem. 2025, 64, 1788–1797. [pdf]

[743]

J. S. Schneider, V. Zeh, J. Klopf, P. M. Schneider, J. Bachmann, I. Krummenacher, H. Braunschweig, H. Helten

Poly(Ferrocenylene Iminoborane) and the Merging of 1,1’-Ferrocenylene with p-Phenylene Iminoborane Building Blocks into Alternating Copolymers, Oligomers, and Macrocycles

Chem. Eur. J. 2025, 31, e202404533. [pdf]

[742]

Y. Zhang, A. Matler, J. Krebs, I. Krummenacher, Q. Ye, H. Braunschweig, T. B. Marder, L. Ji

Emission-Tunable B←N Lewis Pair-Functionalized Naphthalenes: Synthesis, Structures, and Properties

Chem. Eur. J. 2025, 31, e202403973. [pdf]

[741]

F. Saal, V. Brancaccio, K. Radacki, H. Braunschweig, P. Ravat

Spring-Like Behavior in [8]Helicene Diimides: How Helical Pitch Governs Optical Anisotropy and Electronic Conjugation

ChemRxiv 2025, doi: 10.26434/chemrxiv-2025-m6825. [link]

[740]

S. Dotzauer, S. Kar, T. Swoboda, C. Weidemann, A. Häfner, R. D. Dewhurst, H. Braunschweig

Synthesis of base-free boriranes and their conversion to borirenes using strong reductant

Dalton Trans. 2025, 54, 3857–3862. [pdf]

[739]

B. Chakraborty, R. R. Hazarika, H. Braunschweig, A. K. Phukan

Binding of base-stabilized borylenes with transition metals and formation of metal only Lewis pairs

Dalton Trans. 2025, 54, 842–850. [pdf]

[738]

L. Euringer, M. Holzapfel, I. Krummenacher, H. Braunschweig, C. Lambert

Switching from Transition-State Theory to Solvent-Controlled Adiabatic Charge-Transfer Regime in Bis-Triarylamine Mixed Valence Radical Cations by Modification of the Bridge Electron Density

J. Phys. Chem. B 2025, 129, 4197–4206. [pdf]