T. E. Stennett, A. Jayaraman, T. Brückner, L. Schneider, H. Braunschweig 

Hydrophosphination of Boron-Boron Multiple Bonds
2019, submitted.



S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Hermann, V. Paprocki, R. Drescher, I. Krummenacher, H. Braunschweig 

Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
2019, submitted.



J. T. Goettel, H. Gao, S. Dotzauer, H. Braunschweig 

MeCAAC=N−: A Cyclic (Alkyl)(Amino)Carbene Imino Ligand
2019, submitted.



T. Ribbeck, C. Kerpen, C. Schmidle, F. Keppner, J. A. P. Sprenger, M. Arrowsmith, H. Braunschweig, N. V. Igant’ev, M. Finze 

The Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties
2019, submitted.



V. Paprocki, P. Hrobárik, K. L. M. Harriman, M. S. Luff, T. Kupfer, M. Kaupp, M. Murugesu, H. Braunschweig 

Remarkably Strong η6-Coordination of a Neutral Arene to f-Block Elements
2019, submitted.



W. C. Ewing, T. Dellermann, Y. T. A. Wong, J. D. Mattock, A. Vargas, D. L. Bryce, H. Braunschweig 

Metal-free π-Complexes Between Diborynes and Main Group Atoms
2019, submitted.



Z.-F. Jiao, Y.-M. Tian, B. Zhang, C.-H. Hao, Y. Qiao, Y.-X. Wang, Y. Qin, U. Radius, H. Braunschweig, T. B. Marder, X.-N. Guo, X.-Y. Guo 

High Photocatalytic Activity of a NiO nanodot-decorated Pd/SiC Catalyst for the Suzuki-Miyaura Cross-coupling of Aryl Bromides and Chlorides in Air
2018, submitted.



C. Lenczyk, D. K. Roy, K. Oberdorf, J. Nitsch, R. D. Dewhurst, K. Radacki, J.-F. Halet, T. B. Marder, F. M. Bickelhaupt, H. Braunschweig 

Ruthenium-Templated Construction of an Arylated B4 Chain by Dihydroborane Dehydrocoupling
Chem. Eur. J. 201925, accepted.



J. Merz, M. Dietz, Y. Vonhausen, F. Wöber, A. Friedrich, D. Sieh, I. Krummenacher, H. Braunschweig, M. Moos, M. Holzapfel, C. Lambert, T. B. Marder 

Synthesis, Photophysical and Electronic Properties of New Red to NIR Emitting Donor-Acceptor Pyrene Derivatives
Chem. Eur. J. 201925, accepted.



U. Schmidt, L. Werner, M. Arrowsmith, A. Deißenberger, A. Hermann, A. Hofmann, S. Ullrich, J. D. Mattock, A. Vargas, H. Braunschweig 

Trans-selective Insertional Dihydroboration of a cis-Diborene: Synthesis of Linear sp3-sp2-sp3-Triboranes and Subsequent Cationization
Angew. Chem. 2019131; Angew. Chem. Int. Ed. 201958, accepted.



Z. Huang, S. Wang, R. D. Dewhurst, N. V. Ignat'ev, M. Finze, H. Braunschweig 

Boron: Its role in energy related reserach and applications
Angew. Chem. 2019131; Angew. Chem. Int. Ed. 201958, accepted.



M. Rang, H. Braunschweig 

Die Verkettung zweier Stickstoffmoleküle
Chem. Unserer Zeit 201953, accepted.



Y. Hattori, E. Michail, A. Schmiedel, M. Moos, M. Holzapfel, I. Krummenacher, H. Braunschweig, U. Müller, J. Pflaum, C. Lambert 

Luminescent mono-, di-, and tri-radicals: bridging polychlorinated triarylmethyl radicals by triarylamines and triarylboranes
Chem. Eur. J. 201925, accepted.



I. Krummenacher, J. K. Schuster, H. Braunschweig 

Synthesis and Reactivity of Bora- and Boratabenzenes
Patai´s Chemistry of Functional Groups 2019, Eds. I. Marek, M. Gandelman, DOI: 10.1002/9780470682531.PAT0969.




M.-A. Légaré, M. Rang, G. Bélanger-Chabot, J. I. Schweizer, I. Krummenacher, R. Bertermann, M. Arrowsmith, M. C. Holthausen, H. Braunschweig 

The reductive coupling of dinitrogen

Science 2019, 363, 1329–1332. [pdf]


Highlighted in:

"Boron helps to gently couple dinitrogen", M. Jacoby, C&EN 2019, 99(12)[link]

"Widerspenstiger Stickstoff gezähmt", Spektrogramm, Spektrum der Wissenschaft,  2019, Ausgabe 6, 8. [pdf]


Angew. Chem.


G. Bélanger-Chabot, H. Braunschweig 

Hexahalodiborate Dianions: A New Family of Binary Boron Halides

Angew. Chem. 2019, 131, 14408–14412; [pdf] Angew. Chem. Int. Ed. 2019, 58, 14270–14274. [pdf]


Highlighted in:

"Back to basics", T. Ortner, Nature Reviews Chemistry 2019, 3, 564. [link]



C. Pranckevicius, C. Herok, F. Fantuzzi, B. Engels, H. Braunschweig 

Bond-Strengthening Backdonation in Aminoborylene-Stabilized Aminoborylenes: At the Intersection of Borylenes and Diborenes

Angew. Chem. 2019, 131, 13025–13029; [pdf] Angew. Chem. Int. Ed. 2019, 58, 12893–12897. [pdf]



M. Dömling, M. Arrowsmith, U. Schmidt, L. Werner, A. C. Castro, J. O. C. Jiménez-Halla, R. Bertermann, J. H. Müssig, D. Prieschl, H. Braunschweig 

Spontaneous trans-Selective Transfer Hydrogenation of Apolar Boron-Boron Double Bonds

Angew. Chem. 2019, 131, 9884–9889; [pdf] Angew. Chem. Int. Ed. 2019, 58, 9782–9786. [pdf]



A. Hofmann, M.-A. Légaré, L. Wüst, H. Braunschweig 

Heterodiatomic Multiple Bonding in Group 13: A Complex with a Boron-Alumnium π Bond Reduces CO2

Angew. Chem. 2019, 131, 9878–9883; [pdf] Angew. Chem. Int. Ed. 2019, 58, 9776–9781. [pdf]



T. E. Stennett, P. Bissinger, S. Griesbeck, S. Ullrich, I. Krummenacher, M. Auth, A. Sperlich, M. Stolte, K. Radacki, C.-J. Yao, F. Würthner, A. Steffen, T. B. Marder, H. Braunschweig 

Near-Infrared Quadrupolar Chromophores Combining Three-Coordinate Boron-Based Superdonor and Superacceptor Units

Angew. Chem. 2019, 131, 6516–6521; [pdf] Angew. Chem. Int. Ed. 2019, 58, 6449–6454. [pdf]



J. H. Müssig, M. Thaler, R. D. Dewhurst, V. Paprocki, J. Seufert, J. D. Mattock, A. Vargas, H. Braunschweig 

Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds

Angew. Chem. 2019, 131, 4451–4456; [pdf] Angew. Chem. Int. Ed. 2019, 58, 4405–4409. [pdf]



A. Hofmann, C. Pranckevicius, T. Tröster, H. Braunschweig 

Aluminum(I)/Boron(III) Redox Reactions

Angew. Chem. 2019, 131, 3664–3668; [pdf] Angew. Chem. Int. Ed. 2019, 58, 3625–3629. [pdf]



Q. Zhao, R. D. Dewhurst, H. Braunschweig, X. Chen 

A New Perspective on Borane Chemistry: The Nucleophilicity of the of the B-H Bonding Pair Electrons

Angew. Chem. 2019, 131, 3302–3313; [pdf] Angew. Chem. Int. Ed. 2019, 58, 3268–3278. [pdf]



A. Deißenberger, E. Welz, R. Drescher, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig 

A New Class of Neutral Boron-Based Diradicals Spanned by a Two-Carbon-Atom Bridge

Angew. Chem. 2019, 131, 1857–1861; [pdf] Angew. Chem. Int. Ed. 2019, 58, 1842–1846. [pdf]



F. Lindl, S. Lin, I. Krummenacher, C. Lenczyk, A. Stoy, M. Müller, Z. Lin, H. Braunschweig 

1,2,3-Diazaborinine: A BN Analog of Pyridine by Ring Expansion of a Borole with an Organic Azide

Angew. Chem. 2019, 131, 344–348; [pdf] Angew. Chem. Int. Ed. 2019, 58, 338–342. [pdf]

J. Am. Chem. Soc.


S. K. Mellerup, Y. Cui, F. Fantuzzi, P. Schmid, J. T. Goettel, G. Bélanger-Chabot, M. Arrowsmith, I. Krummenacher, Q. Ye, V. Engel, B. Engels, H. Braunschweig 

Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions

J. Am. Chem. Soc. 2019, 141, 16954–16960. [pdf]



T. Brückner, T. E. Stennett, M. Heß, H. Braunschweig 

Single and Double Hydroboration of B-B Triple Bonds and Convergent Routes to a Cationic Tetraborane

J. Am. Chem. Soc. 2019, 141, 14898–14903. [pdf]

Chem. Rev.


M.-A. Légaré, C. Pranckevicius, H. Braunschweig 

Metallomimetic Chemistry of Boron

Chem. Rev. 2019, 119, 8231–8261. [pdf]

Coord. Chem. Rev.


J. T. Goettel, H. Braunschweig 

Recent Advances in Boron-Centered Ligands and Their Transition Metal Complexes

Coord. Chem. Rev. 2019, 184–200. [link]

Chem. Sci.


A. Schuhmann, F. Reiß, H. Jiao, J. Rabeah, J.-E. Siewert, I. Krummenacher, H. Braunschweig, C. Hering-Junghans 

A selective route to aryl-triphosphiranes and their titanocne-induced fragmentation

Chem. Sci. 2019, 10, 7859–7867. [pdf]



J. Merz, A. Steffen, J. Nitsch, J. Fink, C. B. Schürger, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Moos, D. Mims, C. Lambert, T. B. Marder 

Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-aubstituted ortho-perylenes displaying four reversible oxidations or reductions

Chem. Sci. 2019, 10, 7516–7534. [pdf]



T. Brückner, R. D. Dewhurst, T. Dellermann, M. Müller, H. Braunschweig 

Mild synthesis of diboryldiborenes by diboration of B-B triple bonds

Chem. Sci. 2019, 10, 7375–7378. [pdf]



M. Arrowsmith, J. I. Schweizer, M. Heinz, M. Härterich, I. Krummenacher, M. C. Holthausen, H. Braunschweig 

Synthesis and Reduction Chemistry of Mixed-Lewis-Base-Stabilized Chloroborylenes

Chem. Sci. 2019, 10, 5095–5103. [pdf]



S. Liu, M.-A. Légaré, A. Hofmann, A. Rempel, S. Hagspiel, H. Braunschweig 

Synthesis of unsymmetrical B2E2 and B2E3 heterocycles by borylene insertion into boradichalcogeniranes

Chem. Sci. 2019, 10, 4662–4666. [pdf]



A. Hofmann, T. Tröster, T. Kupfer, H. Braunschweig 

Monomeric Cp3tAl(I): synthesis, reactivity, and the concept of valence isomerism

Chem. Sci. 2019, 10, 3421–3428. [pdf]

Chem. Eur. J.


J. He, F. Rauch, A. Friedrich, D. Sieh, T. Ribbeck, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder 

N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D-π-A Compounds

Chem. Eur. J. 2019, 25, 13777–13784. [pdf]



T. Thiess, S. K. Mellerup, H. Braunschweig 

B-B Cleavage and Ring-Expansion of a 1,4,2,3-Diazadiborinine with N-Heterocyclic Carbenes

Chem. Eur. J. 2019, 25, 13572–13578. [pdf]



C. Lenczyk, D. K. Roy, J. Nitsch, K. Radacki, F. Rauch, R. D. Dewhurst, F. M. Bickelhaupt, T. B. Marder, H. Braunschweig 

Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes

Chem. Eur. J. 2019, 25, 13566–13571. [pdf]



L. Ji, S. Hahn, P. Biegger, H. Reiss, J. Han, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Moos, J. Freudenberg, C. Lambert, A. Dreuw, T. B. Marder, U. H. F. Bunz 

Mono- and Dianion of a Bis(benzobuta)teraazapentacene Derivative

Chem. Eur. J. 2019, 25, 9840–9845. [pdf]



L. Englert, A. Stoy, M. Arrowsmith, J. H. Müssig, M. Thaler, A. Deißenberger, A. Häfner, J. Böhnke, F. Hupp, J. Seufert, J. Mies, A. Damme, T. Dellermann, K. Hammond, T. Kupfer, K. Radacki, T. Thiess, H. Braunschweig 

Stable Lewis Base Adducts of Tetrahalodiboranes: Synthetic Methods and Structural Diversity

Chem. Eur. J. 2019, 25, 8612–8622. [pdf]


Highlighted in:

"Spotlights on our Sister Journals", Angew. Chem. 2019, 131, 9772–9776; [pdf] Angew. Chem. Int. Ed 2019, 58, 9670–9674. [pdf]



C. Lenczyk, D. K. Roy, B. Ghosh, J. Schwarzmann, A. K. Phukan, H. Braunschweig 

First Bis(σ)-borane Complexes of Group 6 Transition Metals: Experimental and Theoretical Studies

Chem. Eur. J. 2019, 25, 8585–8589. [pdf]



M. Meier, L. Ji, J. Nitsch, I. Krummenacher, A. Deißenberger, D. Auerhammer, M. Schäfer, T. B. Marder, H. Braunschweig 

Preparation and Characterization of a π-Conjugated Donor-Acceptor System Containing the Strongly Electron-Accepting Tetraphenylborolyl Unit

Chem. Eur. J. 2019, 25, 4707–4712. [pdf]

Chem. Commun.


D. Prieschl, M. Dietz, J. H. Müssig, K. Wagner, I. Krummenacher, H. Braunschweig 

Pseudodiborenes: hydride-bridged diboranes(5) as two-electron reductants of chalcogens

Chem. Commun. 2019, 55, 9781–9784. [pdf]



A. J. Martínez-Martínez, A. R. Kennedy, V. Paprocki, F. Fantuzzi, R. D. Dewhurst, C. T. O'Hara, H. Braunschweig, R. E. Mulvey 

Selective mono- and dimetallation of a group 3 sandwich complex

Chem. Commun. 2019, 55, 9677–9680. [pdf]



T. Brückner, M. Arrowsmith, M. Heß, K. Hammond, M. Müller, H. Braunschweig 

Synthesis of fused B,N-heterocycles by alkyne cleavage, NHC ring-expansion and C-H activation at a diboryne

Chem. Commun. 2019, 55, 6700–6703. [pdf]

Inorg. Chem.


J. K. Schuster, D. K. Roy, C. Lenczyk, J. Mies, H. Braunschweig 

New Outcomes of Beryllium Chemistry: Lewis Base Adducts for Salt Elimination Reactions

Inorg. Chem. 2019, 58, 2652–2658. [pdf]

Dalton Trans.


J. H. Müssig, T. E. Stennett, U. Schmidt, R. D. Dewhurst, L. Mailänder, H. Braunschweig 

Oxidative addition of arsenic halides to platinum(0)

Dalton Trans. 2019, 48, 3547–3550. [pdf]

Phys. Chem. Chem. Phys.


S. Y. Ketkov, S. Y. Tzeng, E. A. Rychagova, L. V. Kalakutskaya, M. Fuss, H. Braunschweig, W.-B. Tzeng 

Rydberg state mediated multiphoton ionization of (η7-C7H7)(η5-C5H5)Cr: DFT-supported experimental insights into molecular and electronic structures of excited sandwich complexes

Phys. Chem. Chem. Phys. 2019, 21, 9665–9671. [pdf]