Publications 2019



[536]

J. Merz, A. Steffen, J. Nitsch, J. Fink, C. B. Schürger, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Moos, D. Mims, C. Lambert, T. B. Marder 

Synthesis, Photophysical and Electronic Properties of Tetra-Donor- or Acceptor-Substituted ortho-Perylenes Displaying Four Reversible Oxidations or Reductions
2019, submitted.

 

[535]

A. Schuhmann, F. Reiß, H. Jiao, J. Rabeah, I. Krummenacher, H. Braunschweig, C. Hering-Junghans 

Selective Triphosphirane to P2 Conversion
2019, submitted.

 

[534]

L. Ji, S. Hahn, P. Biegger, J. Han, A. Friedrich, I. Krummenacher, H. Braunschweig, M. Moos, J. Freudenberg, C. Lambert, A. Dreuw, T. B. Marder, U. H. F. Bunz 

Mono- and Dianion of a Bis(benzobuta)teraazapentacene Derivative
2019, submitted.

 

[533]

A. J. Martínez-Martínez, A. R. Kennedy, V. Paprocki, F. Fantuzzi, R. D. Dewhurst, C. T. O'Hara, H. Braunschweig, R. E. Mulvey 

Selective Mono- and Dimetallation of a Group 3 Sandwich Complex
2019, submitted.

 

[532]

W. C. Ewing, T. Dellermann, Y. T. A. Wong, J. D. Mattock, A. Vargas, D. L. Bryce, H. Braunschweig 

Metal-free π-Complexes Between Diborynes and Main Group Atoms
2019, submitted.

 

[531]

T. Brückner, R. D. Dewhurst, T. Dellermann, M. Müller, H. Braunschweig 

Synthesis of Air- and Water-Stable Diborenes by Diboration of B-B Triple Bonds
2019, submitted.

 

[530]

Z.-F. Jiao, Y.-M. Tian, B. Zhang, C.-H. Hao, Y. Qiao, Y.-X. Wang, Y. Qin, U. Radius, H. Braunschweig, T. B. Marder, X.-N. Guo, X.-Y. Guo 

High Photocatalytic Activity of a NiO nanodot-decorated Pd/SiC Catalyst for the Suzuki-Miyaura Cross-coupling of Aryl Bromides and Chlorides in Air
2018, submitted.

 

[529]

T. Brückner, M. Arrowsmith, M. Heß, K. Hammond, M. Müller, H. Braunschweig 

Synthesis of fused B,N-heterocycles by alkyne cleavage, NHC ring-expansion and C-H activation at a diboryne

Chem. Commun. 2019, 55, accepted.

 

[528]

C. Lenczyk, D. K. Roy, B. Ghosh, J. Schwarzmann, A. K. Phukan, H. Braunschweig 

First Bis(σ)-borane Complexes of Group 6 Transition Metals: Experimental and Theoretical Studies

Chem. Eur. J. 2019, 25, accepted.

 

[527]

M. Dömling, M. Arrowsmith, U. Schmidt, L. Werner, A. C. Castro, J. O. C. Jiménez-Halla, J. H. Müssig, D. Prieschl, H. Braunschweig 

Spontaneous trans-Selective Transfer Hydrogenation of Apolar B=B Double Bonds
Angew. Chem. 2019131; Angew. Chem. Int. Ed. 201958, accepted.

 

[526]

L. Englert, A. Stoy, M. Arrowsmith, J. H. Müssig, M. Thaler, A. Deißenberger, A. Häfner, J. Böhnke, F. Hupp, J. Seufert, J. Mies, A. Damme, T. Dellermann, K. Hammond, T. Kupfer, K. Radacki, T. Thiess, H. Braunschweig 

Stable Lewis Base Adducts of Tetrahalodiboranes: Synthetic Methods and Structural Diversity

Chem. Eur. J. 2019, 25, accepted.

 

[525]

I. Krummenacher, J. K. Schuster, H. Braunschweig 

Synthesis and Reactivity of Bora- and Boratabenzenes
Patai´s Chemistry of Functional Groups 2019, Eds. I. Marek, M. Gandelman, DOI: 10.1002/9780470682531.PAT0969.

 

[524]

A. Hofmann, M.-A. Légaré, L. Wüst, H. Braunschweig 

Heterodiatomic Multiple Bonding in Group 13: A Complex with a B-Al π Bond Reduces CO2

Angew. Chem. 2019131; Angew. Chem. Int. Ed. 201958, accepted.

 

[523]

M.-A. Légaré, C. Pranckevicius, H. Braunschweig 

The Metallomimetic Chemistry of Boron
Chem. Rev. 2019119, accepted.



Science

[522]

M.-A. Légaré, M. Rang, G. Bélanger-Chabot, J. I. Schweizer, I. Krummenacher, R. Bertermann, M. Arrowsmith, M. C. Holthausen, H. Braunschweig 

The reductive coupling of dinitrogen

Science 2019, 363, 1329–1332. [pdf]



Angew. Chem.

[521]

T. E. Stennett, P. Bissinger, S. Griesbeck, S. Ullrich, I. Krummenacher, M. Auth, A. Sperlich, M. Stolte, K. Radacki, C.-J. Yao, F. Würthner, A. Steffen, T. B. Marder, H. Braunschweig 

Near-Infrared Quadrupolar Chromophores Combining Three-Coordinate Boron-Based Superdonor and Superacceptor Units

Angew. Chem. 2019, 131, 6516–6521; [pdf] Angew. Chem. Int. Ed. 2019, 58, 6449–6454. [pdf]

 

[520]

J. H. Müssig, M. Thaler, R. D. Dewhurst, V. Paprocki, J. Seufert, J. D. Mattock, A. Vargas, H. Braunschweig 

Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds

Angew. Chem. 2019, 131, 4451–4456; [pdf] Angew. Chem. Int. Ed. 2019, 58, 4405–4409. [pdf]

 

[519]

A. Hofmann, C. Pranckevicius, T. Tröster, H. Braunschweig 

Aluminum(I)/Boron(III) Redox Reactions

Angew. Chem. 2019, 131, 3664–3668; [pdf] Angew. Chem. Int. Ed. 2019, 58, 3625–3629. [pdf]

 

[518]

Q. Zhao, R. D. Dewhurst, H. Braunschweig, X. Chen 

A New Perspective on Borane Chemistry: The Nucleophilicity of the of the B-H Bonding Pair Electrons

Angew. Chem. 2019, 131, 3302–3313; [pdf] Angew. Chem. Int. Ed. 2019, 58, 3268–3278. [pdf]

 

[517]

A. Deißenberger, E. Welz, R. Drescher, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig 

A New Class of Neutral Boron-Based Diradicals Spanned by a Two-Carbon-Atom Bridge

Angew. Chem. 2019, 131, 1857–1861; [pdf] Angew. Chem. Int. Ed. 2019, 58, 1842–1846. [pdf]

 

[516]

F. Lindl, S. Lin, I. Krummenacher, C. Lenczyk, A. Stoy, M. Müller, Z. Lin, H. Braunschweig 

1,2,3-Diazaborinine: A BN Analog of Pyridine by Ring Expansion of a Borole with an Organic Azide

Angew. Chem. 2019, 131, 344–348; [pdf] Angew. Chem. Int. Ed. 2019, 58, 338–342. [pdf]



Coor. Chem. Rev.

[515]

J. T. Goettel, H. Braunschweig 

Recent Advances in Boron-Centered Ligands and Their Transition Metal Complexes

Coord. Chem. Rev. 2019, 184–200. [link]



Chem. Sci.

[514]

M. Arrowsmith, J. I. Schweizer, M. Heinz, M. Härterich, I. Krummenacher, M. C. Holthausen, H. Braunschweig 

Synthesis and Reduction Chemistry of Mixed-Lewis-Base-Stabilized Chloroborylenes

Chem. Sci. 2019, 10, 5095–5103. [pdf]

 

[513]

S. Liu, M.-A. Légaré, A. Hofmann, A. Rempel, S. Hagspiel, H. Braunschweig 

Synthesis of unsymmetrical B2E2 and B2E3 heterocycles by borylene insertion into boradichalcogeniranes

Chem. Sci. 2019, 10, 4662–4666. [pdf]

 

[512]

A. Hofmann, T. Tröster, T. Kupfer, H. Braunschweig 

Monomeric Cp3tAl(I): synthesis, reactivity, and the concept of valence isomerism

Chem. Sci. 2019, 10, 3421–3428. [pdf]



Chem. Eur. J.

[511]

M. Meier, L. Ji, J. Nitsch, I. Krummenacher, A. Deißenberger, D. Auerhammer, M. Schäfer, T. B. Marder, H. Braunschweig 

Preparation and Characterization of a π-Conjugated Donor-Acceptor System Containing the Strongly Electron-Accepting Tetraphenylborolyl Unit

Chem. Eur. J. 2019, 25, 4707–4712. [pdf]



Inorg. Chem.

[510]

J. K. Schuster, D. K. Roy, C. Lenczyk, J. Mies, H. Braunschweig 

New Outcomes of Beryllium Chemistry: Lewis Base Adducts for Salt Elimination Reactions

Inorg. Chem. 2019, 58, 2652–2658. [pdf]



Dalton Trans.

[509]

J. H. Müssig, T. E. Stennett, U. Schmidt, R. D. Dewhurst, L. Mailänder, H. Braunschweig 

Oxidative addition of arsenic halides to platinum(0)

Dalton Trans. 2019, 48, 3547–3550. [pdf]



Phys. Chem. Chem. Phys.

[508]

S. Y. Ketkov, S. Y. Tzeng, E. A. Rychagova, L. V. Kalakutskaya, M. Fuss, H. Braunschweig, W.-B. Tzeng 

Rydberg state mediated multiphoton ionization of (η7-C7H7)(η5-C5H5)Cr: DFT-supported experimental insights into molecular and electronic structures of excited sandwich complexes

Phys. Chem. Chem. Phys. 2019, 21, 9665–9671. [pdf]