Publications 2019



[526]

M. Arrowsmith, J. I. Schweizer, M. Heinz, M. Härterich, I. Krummenacher, M. C. Holthausen, H. Braunschweig 

Synthesis and Reduction Chemistry of Mixed-Lewis-Base-Stabilized Chloroborylenes

2019, submitted.

 

[525]

A. Hofmann, M.-A. Légaré, L. Wüst, H. Braunschweig 

Heterodiatomic Multiple Bonding in Group 13: A Complex with a B-Al π Bond Reduces CO2

2019, submitted.

 

[524]

W. C. Ewing, T. Dellermann, Y. T. A. Wong, J. D. Mattock, A. Vargas, D. L. Bryce, H. Braunschweig 

Metal-free π-Complexes Between Diborynes and Main Group Atoms
2019, submitted.

 

[523]

T. Brückner, R. D. Dewhurst, T. Dellermann, M. Müller, H. Braunschweig 

Synthesis of Air- and Water-Stable Diborenes by Diboration of B-B Triple Bonds
2019, submitted.

 

[522]

Z.-F. Jiao, Y.-M. Tian, B. Zhang, C.-H. Hao, Y. Qiao, Y.-X. Wang, Y. Qin, U. Radius, H. Braunschweig, T. B. Marder, X.-N. Guo, X.-Y. Guo 

High Photocatalytic Activity of a NiO nanodot-decorated Pd/SiC Catalyst for the Suzuki-Miyaura Cross-coupling of Aryl Bromides and Chlorides in Air
2018, submitted.

 

[521]

S. Liu, M.-A. Légaré, A. Hofmann, A. Rempel, S. Hagspiel, H. Braunschweig 

Synthesis of Unsymmetrical B2E2 and B2E3 Heterocycles by Borylene Insertion into Boradichalcogeniranes
Chem. Sci. 201910, accepted.

 

[520]

T. E. Stennett, P. Bissinger, S. Griesbeck, S. Ullrich, I. Krummenacher, M. Auth, A. Sperlich, M. Stolte, K. Radacki, C.-J. Yao, F. Würthner, A. Steffen, T. B. Marder, H. Braunschweig 

Near-infrared quadrupolar chromophores combining three-coordinate boron-based superdonor and-acceptor units
Angew. Chem. 2019131; Angew. Chem. Int. Ed. 201958, accepted.

 

[519]

M. Meier, L. Ji, J. Nitsch, I. Krummenacher, A. Deißenberger, D. Auerhammer, M. Schäfer, T. B. Marder, H. Braunschweig 

Preparation and Characterization of a π-Conjugated Donor-Acceptor System Containing the Strongly Electron-Accepting Tetraphenylborolyl Unit
Chem. Eur. J. 201925, accepted.

 

[518]

M.-A. Légaré, C. Pranckevicius, H. Braunschweig 

The Metallomimetic Chemistry of Boron
Chem. Rev. 2019119, accepted.



Science

[517]

M.-A. Légaré, M. Rang, G. Bélanger-Chabot, J. I. Schweizer, I. Krummenacher, R. Bertermann, M. Arrowsmith, M. C. Holthausen, H. Braunschweig 

The reductive coupling of dinitrogen

Science 2019, 363, 1329–1332. [pdf]



Angew. Chem.

[516]

J. H. Müssig, M. Thaler, R. D. Dewhurst, V. Paprocki, J. Seufert, J. D. Mattock, A. Vargas, H. Braunschweig 

Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds

Angew. Chem. 2019, 131, 4451–4456; [pdf] Angew. Chem. Int. Ed. 2019, 58, 4405–4409. [pdf]

 

[515]

A. Hofmann, C. Pranckevicius, T. Tröster, H. Braunschweig 

Aluminum(I)/Boron(III) Redox Reactions

Angew. Chem. 2019, 131, 3664–3668; [pdf] Angew. Chem. Int. Ed. 2019, 58, 3625–3629. [pdf]

 

[514]

Q. Zhao, R. D. Dewhurst, H. Braunschweig, X. Chen 

A New Perspective on Borane Chemistry: The Nucleophilicity of the of the B-H Bonding Pair Electrons

Angew. Chem. 2019, 131, 3302–3313; [pdf] Angew. Chem. Int. Ed. 2019, 58, 3268–3278. [pdf]

 

[513]

A. Deißenberger, E. Welz, R. Drescher, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig 

A New Class of Neutral Boron-Based Diradicals Spanned by a Two-Carbon-Atom Bridge

Angew. Chem. 2019, 131, 1857–1861; [pdf] Angew. Chem. Int. Ed. 2019, 58, 1842–1846. [pdf]

 

[512]

F. Lindl, S. Lin, I. Krummenacher, C. Lenczyk, A. Stoy, M. Müller, Z. Lin, H. Braunschweig 

1,2,3-Diazaborinine: A BN Analog of Pyridine by Ring Expansion of a Borole with an Organic Azide

Angew. Chem. 2019, 131, 344–348; [pdf] Angew. Chem. Int. Ed. 2019, 58, 338–342. [pdf]



Coor. Chem. Rev.

[511]

J. T. Goettel, H. Braunschweig 

Recent Advances in Boron-Centered Ligands and Their Transition Metal Complexes

Coord. Chem. Rev. 2019, 184–200. [link]



Chem. Sci.

[510]

A. Hofmann, T. Tröster, T. Kupfer, H. Braunschweig 

Monomeric Cp3tAl(I): synthesis, reactivity, and the concept of valence isomerism

Chem. Sci. 2019, 10, 3421–3428. [pdf]



Inorg. Chem.

[509]

J. K. Schuster, D. K. Roy, C. Lenczyk, J. Mies, H. Braunschweig 

New Outcomes of Beryllium Chemistry: Lewis Base Adducts for Salt Elimination Reactions

Inorg. Chem. 2019, 58, 2652–2658. [pdf]



Dalton Trans.

[508]

J. H. Müssig, T. E. Stennett, U. Schmidt, R. D. Dewhurst, L. Mailänder, H. Braunschweig 

Oxidative addition of arsenic halides to platinum(0)

Dalton Trans. 2019, 48, 3547–3550. [pdf]