PUBLICATIONS 2021

Angew. Chem.

[611]

S. Hagspiel, F. Fantuzzi, R. D. Dewhurst, A. Gärtner, F. Lindl, A. Lamprecht, H. Braunschweig

Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry

Angew. Chem. 2021, 133, 13780–13784; [pdf] Angew. Chem. Int. Ed. 2021, 60, 13666–13670. [pdf]

 

[610]

T. Brückner, F. Fantuzzi, T. E. Stennett, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig

Isolation of Neutral, Mono-, and Dicationic B2P2 Rings by Diphosphorus Addition to a Boron-Boron Triple Bond

Angew. Chem. 2021, 133, 13774–13779; [pdf] Angew. Chem. Int. Ed. 2021, 60, 13661–13665. [pdf]

 

[609]

M. Crumbach, J. Bachmann, L. Fritze, A. Helbig, I. Krummenacher, H. Braunschweig, H. Helten

Dithiophene-Fused Oxadiborepins and Azadiborepins: A New Class of Highly Fluorescent Heteroaromatics

Angew. Chem. 2021, 133, 9376–9381; [pdf] Angew. Chem. Int. Ed. 2021, 60, 9290–9295. [pdf]

 

[608]

S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, A. Hermann, T. Brückner, H. Braunschweig

Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates

Angew. Chem. 2021, 133, 6519–6524; [pdf] Angew. Chem. Int. Ed. 2021, 60, 6446–6450. [pdf]

 

[607]

J. He, F. Rauch, A. Friedrich, J. Krebs, I. Krummenacher, R. Bertermann, J. Nitsch, H. Braunschweig, M. Finze, T. B. Marder

Phenylpyridyl-fused Boroles: A Unique Coordination Mode and Weak B–N Coordination Induced Dual Fluorescence

Angew. Chem. 2021, 133, 4883–4890; [pdf] Angew. Chem. Int. Ed. 2021, 60, 4833–4840. [pdf]

 

[606]

D. K. Roy, T. Tröster, F. Fantuzzi, R. D. Dewhurst, C. Lenczyk, K. Radacki, C. Pranckevicius, B. Engels, H. Braunschweig

Isolation and Reactivity of an Antiaromatic s-Block Metal Compound

Angew. Chem. 2021, 133, 3856–3863; [pdf] Angew. Chem. Int. Ed. 2021, 60, 3812–3819. [pdf]

 

[605]

M. Rang, F. Fantuzzi, M. Arrowsmith, E. Beck, R. Witte, A. Matler, A. Rempel, T. Bischof, K. Radacki, B. Engels, H. Braunschweig

Reduction and Rearrangement of a Boron(I) Carbonyl Complex

Angew. Chem. 2021, 133, 3000–3005; [pdf] Angew. Chem. Int. Ed. 2021, 60, 2963–2968. [pdf]

 

[604]

T. Brückner, M. Heß, T. E. Stennett, A. Rempel, H. Braunschweig

Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron-Boron Triple Bond

Angew. Chem. 2021, 133, 747–752; [pdf] Angew. Chem. Int. Ed. 2021, 60, 736–741. [pdf]



J. Am. Chem. Soc

[603]

M. Fischer, S. Nees, T. Kupfer, J. T. Goettel, H. Braunschweig, C. Hering-Junghans

Isolable Phospha- and Arsaalumenes
J. Am. Chem. Soc. 2021143, 4106–4111. [pdf]

 

[602]

A. Maiti, F. Zhang, I. Krummenacher, M. Bhattacharyya, S. Mehta, M. Moos, C. Lambert, B. Engels, A. Mondal, H. Braunschweig, P. Ravat, A. Jana

Anionic Boron- and Carbon-Based Hetero-Diradicaloids Spanned by a p-Phenylene Bridge
J. Am. Chem. Soc. 2021143, 3687–3692. [pdf]

 



Chem. Rev.

[601]

Y. –M. Tian, X.-N. Guo, H. Braunschweig, U. Radius, T. B. Marder

Photoinduced Borylation for the Synthesis of Organoboron Compounds

Chem. Rev. 2021, 121, 3561–3597. [pdf]



acc. chem. res.

[600]

K. Saha, D. K. Roy, R. D. Dewhurst, S. Ghosh, H. Braunschweig

Recent Advances in the Synthesis and Reactivity of Transition-Metal σ-Borane/-Borate Complexes

Acc. Chem. Res. 2021, 54, 1260–1273. [pdf]



Chem. Sci.

[599]

S. Hagspiel, D. Elezi, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, M. Härterich, I. Krummenacher, H. Braunschweig

Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity

Chem. Sci. 2021, 12, 7937–7942. [pdf]

 

[598]

R. Rausch, M. Roehr, D. Schmid, I. Krummenacher, H. Braunschweig, F. Würthner

Tuning phenoxyl-substituted diketopyrrolopyrroles from quinoidal to biradical ground states through (hetero-)aromatic linkers

Chem. Sci. 2021, 12, 793–802. [pdf]



J. Org. Chem.

[597]

R. Rausch, A.-M. Krause, I. Krummenacher, H. Braunschweig, F. Würthner

Nitronyl Nitroxide Bifunctionalized Electron–Poor Chromophores: Synthesis of Stable Dye Biradicals by Lewis Acid Promoted Desilylation
J. Org. Chem. 202186, 2447–2457. [pdf]



Chem. Eur. J.

[596]

A. Gärtner, M. Marek, M. Arrowsmith, D. Auerhammer, K. Radacki, D. Prieschl, R. D. Dewhurst, H. Braunschweig

Boron- versus Nitrogen-Centered Nucleophilic Reactivity of (Cyano)hydroboryl Anions: Synthesis of Cyano(hydro)organoboranes and 2-Aza-1,4-diborabutatrienes
Chem. Eur. J. 202127, 9694–9699. [pdf]

 

[595]

M. Heß, I. Krummenacher, T. Dellermann, H. Braunschweig

Rhodium-Mediated Stoichiometric Synthesis of Mono-, Bi-, and Bis-1,2-Azaborinines: 1-Rhoda-3,2-azaboroles as Reactive Precursors
Chem. Eur. J. 202127, 9503–9507. [pdf]

 

[594]

J. Krebs, M. Haehnel, I. Krummenacher, A. Friedrich, H. Braunschweig, M. Finze, L. Ji, T. B. Marder

Synthesis and Structure of an o-Carboranyl-substituted Three-coordinate Borane Radical Anion
Chem. Eur. J. 202127, 8159–8167. [pdf]

 

[593]

P. Schmid, F. Fantuzzi, J. Klopf, N. B. Schröder, R. D. Dewhurst, H. Braunschweig, V. Engel, B. Engels

Twisting versus Delocalization in CAAC- and NHC-stabilized Boron-Based Biradicals: The Role of Sterics and Electronics
Chem. Eur. J. 202127, 5160–5170. [pdf]

 

[592]

G. K. Kole, J. Merz, A. Amar, B. Fontaine, A. Boucekkine, J. Nitsch, S. Lorenzen, A. Friedrich, I. Krummenacher, M. Košćak, H. Braunschweig, I. Piantanida, J.-F. Halet, K. Müller-Buschbaum, T. B. Marder

2- and 2,7-Substituted para-N-Methylpyridinium Pyrenes: Syntheses, Molecular and Electronic Structures, Photophysical, Electrochemical, and Spectroelectrochemical Properties and Binding to Double Stranded (ds)-DNA
Chem. Eur. J. 202127, 2837–2853. [pdf]



Chem. Commun.

[591]

F. Schorr, F. Fantuzzi, R. D. Dewhurst, H. Braunschweig

Dialkynyldiboranes(4) and the selectable reactivity of their C-H, C-C and B-B bonds
Chem. Commun. 202157, 2645–2648. [pdf]



J. Catal.

[590]

Z.-F. Jiao, Y.-M. Tian, X.-N. Guo, U. Radius, H. Braunschweig, T. B. Marder, X.-Y. Guo

Visible-light-driven graphene supported Cu/Pd alloy nanoparticle-catalyzed borylation of alkyl bromides and chlorides in air
J. Catal. 2021395, 258–265. [link]



Organometallics

[589]

L. Wu, R. D. Dewhurst, H. Braunschweig, Z. Lin

C-C versus C-H Activation: Understanding How the Carbene π-Accepting Ability Controls the Intramolecular Reactivities of Mono(carbene)-Stabilized Borylenes
Organometallics 202140, 766–775. [pdf]



dalton trans.

[588]

C. Brunecker, M. Arrowsmith, J. H. Müssig, J. Böhnke, A. Stoy, M. Heß, A. Hofmann, C. Lenczyk, C. Lichtenberg, J. Ramler, A. Rempel, H. Braunschweig

Synthesis and characterisation of boranediyl- and diboranediyl-bridged diplatinum A-frame complexes
Dalton Trans. 202150, 3506–3515. [pdf]

 

[587]

J. He, F. Rauch, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder

Two derivatives of phenylpyridyl-fused boroles with contrasting electronic properties: decreasing and enhancing the electron accepting ability
Dalton Trans. 202150, 355–361. [pdf]



Antioxid. Redox Signal.

[586]

R.-S. Sauer, I. Krummenacher, E. E. Bankoglu, S. Yang, B. Oehler, F. Schöppler, M. Mohammadi, P. Güntzel, A. Ben-Kraeim, U. Holzgrabe, H. Stopper, J. A. Broscheit, H. Braunschweig, N. Roewer, A. Brack, H. Rittner

Stabilization of Delphinidin in Complex with Sulfobutylether-β-Cyclodextrin Allows for Antinociception in Inflammatory Pain
Antioxid. Redox Signal. 202134, 1260–1279. [link]



Z. Anorg. Allg. Chem.

[585]

N. A. Riensch, L. Swoboda, A. Lik, I. Krummenacher, H. Braunschweig, H. Helten

Conjugated Bis(triarylboranes) with Disconnected Conjugation
Z. Anorg. Allg. Chem. 2021647, 421–424. [pdf]