Angew. Chem.


S. Hagspiel, F. Fantuzzi, R. D. Dewhurst, A. Gärtner, F. Lindl, A. Lamprecht, H. Braunschweig

Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry

Angew. Chem. 2021, 133, 13780–13784; [pdf] Angew. Chem. Int. Ed. 2021, 60, 13666–13670. [pdf]



T. Brückner, F. Fantuzzi, T. E. Stennett, I. Krummenacher, R. D. Dewhurst, B. Engels, H. Braunschweig

Isolation of Neutral, Mono-, and Dicationic B2P2 Rings by Diphosphorus Addition to a Boron-Boron Triple Bond

Angew. Chem. 2021, 133, 13774–13779; [pdf] Angew. Chem. Int. Ed. 2021, 60, 13661–13665. [pdf]



M. Crumbach, J. Bachmann, L. Fritze, A. Helbig, I. Krummenacher, H. Braunschweig, H. Helten

Dithiophene-Fused Oxadiborepins and Azadiborepins: A New Class of Highly Fluorescent Heteroaromatics

Angew. Chem. 2021, 133, 9376–9381; [pdf] Angew. Chem. Int. Ed. 2021, 60, 9290–9295. [pdf]



S. Hagspiel, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, A. Hermann, T. Brückner, H. Braunschweig

Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates

Angew. Chem. 2021, 133, 6519–6524; [pdf] Angew. Chem. Int. Ed. 2021, 60, 6446–6450. [pdf]



J. He, F. Rauch, A. Friedrich, J. Krebs, I. Krummenacher, R. Bertermann, J. Nitsch, H. Braunschweig, M. Finze, T. B. Marder

Phenylpyridyl-fused Boroles: A Unique Coordination Mode and Weak B–N Coordination Induced Dual Fluorescence

Angew. Chem. 2021, 133, 4883–4890; [pdf] Angew. Chem. Int. Ed. 2021, 60, 4833–4840. [pdf]



D. K. Roy, T. Tröster, F. Fantuzzi, R. D. Dewhurst, C. Lenczyk, K. Radacki, C. Pranckevicius, B. Engels, H. Braunschweig

Isolation and Reactivity of an Antiaromatic s-Block Metal Compound

Angew. Chem. 2021, 133, 3856–3863; [pdf] Angew. Chem. Int. Ed. 2021, 60, 3812–3819. [pdf]



M. Rang, F. Fantuzzi, M. Arrowsmith, E. Beck, R. Witte, A. Matler, A. Rempel, T. Bischof, K. Radacki, B. Engels, H. Braunschweig

Reduction and Rearrangement of a Boron(I) Carbonyl Complex

Angew. Chem. 2021, 133, 3000–3005; [pdf] Angew. Chem. Int. Ed. 2021, 60, 2963–2968. [pdf]



T. Brückner, M. Heß, T. E. Stennett, A. Rempel, H. Braunschweig

Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron-Boron Triple Bond

Angew. Chem. 2021, 133, 747–752; [pdf] Angew. Chem. Int. Ed. 2021, 60, 736–741. [pdf]

J. Am. Chem. Soc


M. Fischer, S. Nees, T. Kupfer, J. T. Goettel, H. Braunschweig, C. Hering-Junghans

Isolable Phospha- and Arsaalumenes
J. Am. Chem. Soc. 2021143, 4106–4111. [pdf]



A. Maiti, F. Zhang, I. Krummenacher, M. Bhattacharyya, S. Mehta, M. Moos, C. Lambert, B. Engels, A. Mondal, H. Braunschweig, P. Ravat, A. Jana

Anionic Boron- and Carbon-Based Hetero-Diradicaloids Spanned by a p-Phenylene Bridge
J. Am. Chem. Soc. 2021143, 3687–3692. [pdf]


Chem. Rev.


Y. –M. Tian, X.-N. Guo, H. Braunschweig, U. Radius, T. B. Marder

Photoinduced Borylation for the Synthesis of Organoboron Compounds

Chem. Rev. 2021, 121, 3561–3597. [pdf]

acc. chem. res.


K. Saha, D. K. Roy, R. D. Dewhurst, S. Ghosh, H. Braunschweig

Recent Advances in the Synthesis and Reactivity of Transition-Metal σ-Borane/-Borate Complexes

Acc. Chem. Res. 2021, 54, 1260–1273. [pdf]

Chem. Sci.


S. Hagspiel, D. Elezi, M. Arrowsmith, F. Fantuzzi, A. Vargas, A. Rempel, M. Härterich, I. Krummenacher, H. Braunschweig

Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity

Chem. Sci. 2021, 12, 7937–7942. [pdf]



R. Rausch, M. Roehr, D. Schmid, I. Krummenacher, H. Braunschweig, F. Würthner

Tuning phenoxyl-substituted diketopyrrolopyrroles from quinoidal to biradical ground states through (hetero-)aromatic linkers

Chem. Sci. 2021, 12, 793–802. [pdf]

J. Org. Chem.


R. Rausch, A.-M. Krause, I. Krummenacher, H. Braunschweig, F. Würthner

Nitronyl Nitroxide Bifunctionalized Electron–Poor Chromophores: Synthesis of Stable Dye Biradicals by Lewis Acid Promoted Desilylation
J. Org. Chem. 202186, 2447–2457. [pdf]

Chem. Eur. J.


A. Gärtner, M. Marek, M. Arrowsmith, D. Auerhammer, K. Radacki, D. Prieschl, R. D. Dewhurst, H. Braunschweig

Boron- versus Nitrogen-Centered Nucleophilic Reactivity of (Cyano)hydroboryl Anions: Synthesis of Cyano(hydro)organoboranes and 2-Aza-1,4-diborabutatrienes
Chem. Eur. J. 202127, 9694–9699. [pdf]



M. Heß, I. Krummenacher, T. Dellermann, H. Braunschweig

Rhodium-Mediated Stoichiometric Synthesis of Mono-, Bi-, and Bis-1,2-Azaborinines: 1-Rhoda-3,2-azaboroles as Reactive Precursors
Chem. Eur. J. 202127, 9503–9507. [pdf]



J. Krebs, M. Haehnel, I. Krummenacher, A. Friedrich, H. Braunschweig, M. Finze, L. Ji, T. B. Marder

Synthesis and Structure of an o-Carboranyl-substituted Three-coordinate Borane Radical Anion
Chem. Eur. J. 202127, 8159–8167. [pdf]



P. Schmid, F. Fantuzzi, J. Klopf, N. B. Schröder, R. D. Dewhurst, H. Braunschweig, V. Engel, B. Engels

Twisting versus Delocalization in CAAC- and NHC-stabilized Boron-Based Biradicals: The Role of Sterics and Electronics
Chem. Eur. J. 202127, 5160–5170. [pdf]



G. K. Kole, J. Merz, A. Amar, B. Fontaine, A. Boucekkine, J. Nitsch, S. Lorenzen, A. Friedrich, I. Krummenacher, M. Košćak, H. Braunschweig, I. Piantanida, J.-F. Halet, K. Müller-Buschbaum, T. B. Marder

2- and 2,7-Substituted para-N-Methylpyridinium Pyrenes: Syntheses, Molecular and Electronic Structures, Photophysical, Electrochemical, and Spectroelectrochemical Properties and Binding to Double Stranded (ds)-DNA
Chem. Eur. J. 202127, 2837–2853. [pdf]

Chem. Commun.


F. Schorr, F. Fantuzzi, R. D. Dewhurst, H. Braunschweig

Dialkynyldiboranes(4) and the selectable reactivity of their C-H, C-C and B-B bonds
Chem. Commun. 202157, 2645–2648. [pdf]

J. Catal.


Z.-F. Jiao, Y.-M. Tian, X.-N. Guo, U. Radius, H. Braunschweig, T. B. Marder, X.-Y. Guo

Visible-light-driven graphene supported Cu/Pd alloy nanoparticle-catalyzed borylation of alkyl bromides and chlorides in air
J. Catal. 2021395, 258–265. [link]



L. Wu, R. D. Dewhurst, H. Braunschweig, Z. Lin

C-C versus C-H Activation: Understanding How the Carbene π-Accepting Ability Controls the Intramolecular Reactivities of Mono(carbene)-Stabilized Borylenes
Organometallics 202140, 766–775. [pdf]

dalton trans.


C. Brunecker, M. Arrowsmith, J. H. Müssig, J. Böhnke, A. Stoy, M. Heß, A. Hofmann, C. Lenczyk, C. Lichtenberg, J. Ramler, A. Rempel, H. Braunschweig

Synthesis and characterisation of boranediyl- and diboranediyl-bridged diplatinum A-frame complexes
Dalton Trans. 202150, 3506–3515. [pdf]



J. He, F. Rauch, I. Krummenacher, H. Braunschweig, M. Finze, T. B. Marder

Two derivatives of phenylpyridyl-fused boroles with contrasting electronic properties: decreasing and enhancing the electron accepting ability
Dalton Trans. 202150, 355–361. [pdf]

Antioxid. Redox Signal.


R.-S. Sauer, I. Krummenacher, E. E. Bankoglu, S. Yang, B. Oehler, F. Schöppler, M. Mohammadi, P. Güntzel, A. Ben-Kraeim, U. Holzgrabe, H. Stopper, J. A. Broscheit, H. Braunschweig, N. Roewer, A. Brack, H. Rittner

Stabilization of Delphinidin in Complex with Sulfobutylether-β-Cyclodextrin Allows for Antinociception in Inflammatory Pain
Antioxid. Redox Signal. 202134, 1260–1279. [link]

Z. Anorg. Allg. Chem.


N. A. Riensch, L. Swoboda, A. Lik, I. Krummenacher, H. Braunschweig, H. Helten

Conjugated Bis(triarylboranes) with Disconnected Conjugation
Z. Anorg. Allg. Chem. 2021647, 421–424. [pdf]