Publications 2013



Nat. Chem.

[327]

H. Braunschweig, T. Dellermann, R. D. Dewhurst, W. C. Ewing, K. Hammond, J. O. C. Jimenez-Halla, T. Kramer, I. Krummenacher, J. Mies, A. K. Phukan, A. Vargas
Metal-Free binding and coupling of carbon monoxide at a boron-boron triple bond
Nat. Chem. 2013, 5, 1025–1028. [pdf]

 

Highlighted in:

"A reducing role for boron", P. L. Arnold, Nature 2013, 502, 458–459. [pdf]

 

"Bor-Chemie im Aufwind", M. Groß, Chem. unserer Zeit 2013, 47, 340. [pdf]

 

[326]

H. Braunschweig, A. Damme, R. D. Dewhurst, A. Vargas
Bond-strengthening π backdonation in a transition-metal π-diborene complex
Nat. Chem. 2013, 5, 115–121. [pdf]

 

Highlighted in:

"Metal-reinforced bonding", H.-J. Himmel, Nat. Chem. 2013, 5, 88–89. [pdf]

 

"Metall stärkt Doppelbindung", R. Emmerich, Chemie Extra 2013, 1–2, 4. [link]



Angew. Chem.

[325]

H. Braunschweig, V. Dyakonov, B. Engels, Z. Falk, C. Hörl, J. H. Klein, T. Kramer, H. Kraus, I. Krummenacher, C. Lambert, C. Walter
Multiple Reduction States of 2,5-Bis(borolyl)thiophene: Isolation of a Negative Bipoloron by Comproportionation
Angew. Chem. 2013, 125, 13088–13092; [pdf] Angew. Chem. Int. Ed. 2013, 52, 12852–12855. [pdf]

 

[324]

H. Braunschweig, A. Damme, K. Radacki, A. Vargas, Q. Ye
Phosphine-Triggered Co-catenation of :BR and CO on an Iron Atom
Angew. Chem. 2013, 125, 10851–10854; [pdf] Angew. Chem. Int. Ed. 2013, 52, 10657–10660. [pdf]

 

[323]

H. Braunschweig, R. D. Dewhurst, C. Hörl, K. Radacki, C. W. Tate, A. Vargas, Q. Ye
Reductive Borylene-CO Coupling with a Bulky Arylborylene Complex
Angew. Chem. 2013, 125, 10307–10310; [pdf] Angew. Chem. Int. Ed. 2013, 52, 10120–10123. [pdf]

 

[322]

P. Bissinger, H. Braunschweig, A. Damme, T. Kupfer, K. Radacki
An Electron-Precise, Tetrahedral μ3 Boride Complex
Angew. Chem. 2013, 125, 7176–7179; [pdf] Angew. Chem. Int. Ed. 2013, 52, 7038–7041. [pdf]

 

[321]

H. Braunschweig, R. D. Dewhurst
Single, Double, Triple Bonds and Chains: The Formation of Electron-Precise B–B Bonds
Angew. Chem. 2013, 125, 3658–3667; [pdf] Angew. Chem. Int. Ed. 2013, 52, 3574–3583. [pdf]

 

[320]

H. Braunschweig, P. Brenner, R. D. Dewhurst, J. O. C. Jimenez-Halla, T. Kupfer, D. Rais, K. Uttinger
Maximizing Coordinative and Electronic Unsaturation: Three-Coordinate Dicationic Platinum Complexes
Angew. Chem. 2013, 125, 3055–3058; [pdf] Angew. Chem. Int. Ed. 2013, 52, 2981–2984. [pdf]

 

Highlighted in:

"Trendberichte 2013: Koordinationschemie", I. Siewert, M. Walter, Nachrichten aus der Chemie 2014, 62, 237. [pdf]

 

[319]

H. Braunschweig, K. Radacki, R. Shang, C. W. Tate
Reversible Intramolecular Coupling of the Terminal Borylene and a Carbonyl Ligand of [Cp(CO)2Mn=B-tBu]
Angew. Chem. 2013, 125, 757–761; [pdf] Angew. Chem. Int. Ed. 2013, 52, 729–733. [pdf]



J. Am. Chem. Soc.

[318]

J. Bauer, H. Braunschweig, A. Damme, J. O. C. Jimenez-Halla, T. Kramer, K. Radacki, R. Shang, E. Siedler, Q. Ye
Metathesis Reactions of a Manganese Borylene Complex with Polar Heteroatom-Carbon Double Bonds: A Pathway to Previously Inaccessible Carbene Complexes
J. Am. Chem. Soc. 2013, 135, 8726–8734. [pdf]

 

[317]

H. Braunschweig, A. Damme, R. D. Dewhurst, T. Kramer, T. Kupfer, K. Radacki, E. Siedler, A.Trumpp, K. Wagner, C. Werner
Quaternizing Diboranes(4): Highly Divergent Outcomes and an Inorganic Wagner-Meerwein Rearrangement
J. Am. Chem. Soc. 2013, 135, 8702–8707. [pdf]

 

Highlighted in:

"Trendberichte 2013: Anorganische Molekülchemie", R. C. Fischer, J. J. Weigand, Nachrichten aus der Chemie 2014, 62, 219. [pdf]

 

[316]

H. Braunschweig, A. Damme, R. D. Dewhurst, T. Kramer, S. Östreicher, K. Radacki, A. Vargas
Ditopic Amphiphilicity of an Anionic Dimetalloborylene Complex
J. Am. Chem. Soc. 2013, 135, 2313–2320. [pdf]

 

[315]

H. Braunschweig, A. Damme, R. D. Dewhurst, S. Gosh, T. Kramer, B. Pfaffinger, K. Radacki, A. Vargas
Electronic and Structural Effects of Stepwise Borylation and Quaternization on Borirene Aromaticity
J. Am. Chem. Soc. 2013, 135, 1903–1911. [pdf]

 

Highlighted in:

"Trendberichte 2013: Anorganische Molekülchemie", R. C. Fischer, J. J. Weigand, Nachrichten aus der Chemie 2014, 62, 219. [pdf]



Chem. Commun.

[314]

H. Braunschweig, K. Radacki, R. Shang
σ-Coordination of metal-boryl bonds to gold(I)
Chem. Commun. 2013, 49, 9905–9907. [pdf]

 

[313]

H. Braunschweig, A. Damme, K. Radacki, Q. Ye
Synthesis and structure of the first heterodinuclear bis(borylene) complexes
Chem. Commun. 2013, 49, 7593–7595. [pdf]

 

[312]

H. Braunschweig, A. Damme
Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II)
Chem. Commun. 2013, 49, 5216–5218. [pdf]

 

[311]

H. Braunschweig, A. Damme, T. Kupfer
Synthesis of a bicyclic diborane by selective boron carbon bond formation
Chem. Commun. 2013, 49, 2774–2776. [pdf]

 

[310]

H. Braunschweig, R. Bertermann, A. Damme, T. Kupfer
A dinuclear platinum complex featuring the diboran(4)-1,2-diyl Ligand in a μ2-bridging coordination mode
Chem. Commun. 2013, 49, 2439–2441. [pdf]

 

[309]

H. Braunschweig, T. Herbst, K. Radacki, C. W. Tate, A. Vargas
Cyclic (amino)(imino)carbene complexes by borylene transfer to isocyanides
Chem. Commun. 2013, 49, 1702–1704. [pdf]

 

Highlighted in:

"Unprecedented Carbene Ligands", S. K. Ritter, C&EN 2013, 91(6), 31–32. [link]



Chem. Eur. J.

[308]

J. Bauer, S. Bertsch, H. Braunschweig, R. D. Dewhurst, K. Ferkinghoff, C. Hörl, K. Kraft, K. Radacki
Hydridoborylene Complexes and Di-, Tri- and Tetranuclear Borido Complexes with Hydride Ligands
Chem. Eur. J. 2013, 19, 17608–17612. [pdf]

 

[307]

H. Braunschweig, F. Güthlein, L. Mailänder, T. B. Marder
Synthesis of Catechol-, Pinacol-, and Neopentylglycolborane through the Heterogeneous Catalytic B–B Hydrogenolysis of Diboranes(4)
Chem. Eur. J. 2013, 19, 14831–14835. [pdf]

 

[306]

H. Braunschweig, A. Damme, T. Kupfer
Conversion of trans-Diboran(4)yl Platinum Complexes into Their cis-Bisboryl Analogues
Chem. Eur. J. 2013, 19, 14682–14686. [pdf]

 

[305]

P. Bissinger, H. Braunschweig, A. Damme, R. D. Dewhurst, K. Kraft, T. Kramer, K. Radacki
Base-Stabilized Boryl and Cationic Haloborylene Complexes of Iron
Chem. Eur. J. 2013, 19, 13402–13407. [pdf]

 

[304]

J. Bauer, H. Braunschweig, C. Hörl, K. Radacki, J. Wahler
Synthesis of Zwitterionic Cobaltocenium Borate and Borata-alkene Derivatives from a Borole-Radical Anion
Chem. Eur. J. 2013, 19, 13396–13401. [pdf]

 

[303]

T. Arnold, H. Braunschweig, J. O. C. Jimenez-Halla, K. Radacki, S. S. Sen
Simultaneous Fragmentation and Activation of White Phosphorus
Chem. Eur. J. 2013, 19, 9114–9117. [pdf]

 

[302]

J. Bauer, H. Braunschweig, R. D. Dewhurst, K. Radacki
Reactivity of Lewis Basic Platinum Complexes towards Fluoroboranes
Chem. Eur. J. 2013, 19, 8797–8805. [pdf]

 

[301]

G. Bringmann, G. Zhang, T. Büttner, G. Bauckmann, T. Kupfer, H. Braunschweig, R. Brun, V. Mudogo
Jozimine A2: The First Dimeric Dioncophyllaceae-Type Naphthylisoquinoline Alkaloid, with Three Chiral Axes and High Antiplasmodial Activity
Chem. Eur. J. 2013, 19, 916–923. [pdf]

 

[300]

H. Braunschweig, F. Breher, S. Capper, K. Dück, M. Fuß, J. O. C. Jimenez-Halla, I. Krummenacher, T. Kupfer, D. Nied, K. Radacki
Heteroleptic [n]Chromoarenophanes: ansa Complexes Derived from [Cr(η5-C5H5)(η6-C6H6)]
Chem. Eur. J. 2013, 19, 270–281 (VIP). [pdf]



Chem. Soc. Rev.

[299]

H. Braunschweig, R. D. Dewhurst, V. H. Gessner
Transition metal borylene complexes
Chem. Soc. Rev. 2013, 42, 3197–3208. [pdf]



Adv. Organomet. Chem.

[298]

H. Braunschweig, I. Krummenacher, J. Wahler
Free Boroles: The Effect of Antiaromaticity on Their Physical Properties and Chemical Reactivity
Adv. Organomet. Chem. 2013, 61, 1–53. [pdf]



Inorg. Chem.

[297]

H. Braunschweig, F. Hupp, T. Kramer, J. Mager
Structure and Reactivity of Distanna[2]metallocenophanes of Ruthenium and Osmium
Inorg. Chem. 2013, 52, 9060–9065. [pdf]

 

[296]

H. Braunschweig, A. Damme, T. Kupfer
Diboran(4)yl Platinum(II) Complexes
Inorg. Chem. 2013, 52, 7822–7824. [pdf]

 

[295]

H. Braunschweig, K. Radacki, Q. Ye
Synthesis and Structure of a Carbene-stabilized Boraallene Coordinated to Rhodium
Inorg. Chem. 2013, 52, 5639–5641. [pdf]



Organometallics

[294]

H. Braunschweig, A. Damme, C. Hörl, T. Kupfer, J. Wahler
Si–H Bond Activation at the Boron Center of Pentaphenylborole
Organometallics 2013, 32, 6800–6803. [pdf]

 

[293]

H. Braunschweig, J. Maier, K. Radacki, J. Wahler
Ring Expansion of 7-Boranorbornadienes by Coordination with a N-Heterocyclic Carbene
Organometallics 2013, 32, 6353–6359. [pdf]



Eur. J. Inorg. Chem.

[292]

T. Arnold, H. Braunschweig, F. Hupp, K. Radacki, S. S. Sen
Reactions of a [1],[1]Disilamolybdenocenophane with Unsaturated Compounds
Eur. J. Inorg. Chem. 2013, 5027–5032. [pdf]

 

[291]

H. Braunschweig, C.-W. Chiu, D. Gamon, K. Gruß, C. Hörl, T. Kupfer, K. Radacki, J. Wahler
Lewis Acid-Base Adducts of 1-Mesityl- and 1-Chloro-2,3,4,5-tetraphenylborole
Eur. J. Inorg. Chem. 2013, 1525–1530. [pdf]



Austr. J. Chem.

[290]

A. Rammo, I. Bejan, A. Meltzer, K. Radacki, H. Braunschweig, D. Scheschkewitz
1,2-Disilabicyclo[1.1.1]pentan-4-ones from a disilenide and acryloyl chlorides
Austr. J. Chem. 2013, 66, 1311–1314. [link]



Z. anorg. allg. Chem.

[289]

H. Braunschweig, P. Brenner, K. Radacki
Wolfphos in Sheep's Clothing: The First Trinuclear Triboryl- And Other Boryl Platinum Complexes Featuring a Flexible Phosphine Ligand
Z. anorg. allg. Chem. 2013, 639, 1129–1133. [pdf]



Z. Naturforsch.

[288]

H. Braunschweig, P. Brenner, R. D. Dewhurst, K. Radacki
A Base-Stabilized Iodoborylene Complex of Platinum(II)
Z. Naturforsch. 2013, 68b, 747–749. [pdf]



Patent

[287]

H. Braunschweig, F. Güthlein
Transition-metal catalyzed synthesis of diboranes(4)
EP2554547 (A1), 2013. [link]